Methods of testing cement — Report of a test programme — Chemical analysis by x-ray fluorescence
水泥的测试方法——测试计划报告——x射线荧光化学分析
发布日期:
2009-04-20
ISO/TS 12389:2009描述了通过x射线荧光法对水泥进行化学分析的实验室间测试结果。首先,实验室间测试是根据JIS R 5204:2002在日本和亚洲国家进行的。共有30个实验室,其中16个在日本,14个在日本以外,参与了最初的测试计划。2005年,另有12个欧洲实验室根据JIS R 5204的CEN/TC 51/WG 15/TG 1开发的EN 196-2使用相同材料参与了测试。截至本技术报告发布之日,最新版本(ISO 29581-2)正在分发以供技术咨询。
使用的测试样品是符合EN 197-1的CEM I的波特兰水泥以及波特兰水泥和高炉矿渣的混合物。混合物对应于JIS R 5211和EN 197-1的CEM III/A中规定的B级波特兰高炉矿渣水泥的组成。x射线荧光分析用水泥标准物质(编号601A)作为校准标准品,认证标准物质JCA-CRM-1和JCA-CRM-2作为验证物质。
分析的成分包括SiO2、Al2O3、Fe2O3、CaO、MgO、SO3、Na2O、K2O、TiO2、P2O5、MnO和SrO。还测定了烧失量。
ISO循环赛是在接近最佳条件下进行的方法性能研究,具有明确的校准和测量指南。这有利于产生代表理想情况的“最佳实践”值。然而,ISO 29581-2旨在按照“良好实践”操作的实验室的日常条件下使用。介绍了由大量实验室进行的一些国际循环赛的结果,证明了ISO 29581-2作为比较实验室日常性能的手段的适用性。
ISO/TS 12389:2009 describes the results of the inter-laboratory testing of the chemical analysis of cement by x-ray fluorescence. In the first instance, the inter-laboratory testing was carried out in Japan and Asian countries in accordance with JIS R 5204:2002. A total of 30 laboratories, 16 in Japan and 14 outside Japan, participated in the original testing programme. A further 12 European laboratories participated in tests with the same materials in 2005 in accordance with EN 196-2, a development by CEN/TC 51/WG 15/TG 1 of JIS R 5204. The latest version, developed as ISO 29581-2, is, as of the date of publication of this Technical Report, in the process of being circulated for technical enquiry.
The test samples used were Portland cement conforming to CEM I of EN 197-1 and a mixture of Portland cement and blast furnace slag. The mixture corresponded to the composition of Portland blast furnace slag cement, class B, specified in JIS R 5211 and CEM III/A of EN 197-1. Cement reference materials for x-ray fluorescence analysis (No. 601A) are used for the calibration standards, and certified reference materials JCA-CRM-1 and JCA-CRM-2 are used as the validation materials.
Constituents analysed include SiO2, Al2O3, Fe2O3, CaO, MgO, SO3, Na2O, K2O, TiO2, P2O5, MnO and SrO. The loss on ignition is also determined.
The ISO round robin is a method-performance study conducted under close to optimum conditions with clear calibration and measurement guidelines. This is conducive to producing “best practice” values representative of the ideal situation. However, ISO 29581-2 is intended for use under everyday conditions in laboratories that operate to “good practice”. The results are presented for some international round robins carried out by a large number of laboratories demonstrating the suitability of ISO 29581-2 as a means for comparing the everyday performance of laboratories.