Construction of Sherwood Correlation of Bovin Serum Albumin (BSA) and Soluble Microbial Products (SMP) During Nanofiltration
构建牛血清白蛋白(BSA)和可溶性微生物产物(SMP)在纳滤过程中的Sherwood相关性
The soluble microbial products (SMP) which are produced by microorganisms (Flavobacterium and
Staphylococcus in this study) were known as one of the organic nano-colloids that may cause severe
membrane bio-fouling and low bio-stability. The study conducted various characterizations of SMP including
SSF (size, structure, functionality), IR spectra, DBPs, and BDOC/AOC. The SMP exhibited high
molecular weight with ranging from 30,000 to 60,000 g/mol. The mass transfer coefficient of the SMP
can provide very useful information during nanofiltration from the perspective of the concentration
polarization. Lee et al.(2004) experimentally determined the mass transfer coefficient of natural organic
matters (NOM) during filtration using Sherwood correlation experimentally. This study used two
different NF membranes (MWCO < 500 Daltons) to determine the mass transfer coefficient of the SMP
and compared that to the value determined by the CDE model. Both the diffusivity and electromobility of
the SMP were determined by diffusion cell and capillary electrophoresis methods, respectively. The
diffusivity calculated by the Stokes-Einstein equation was dependent only on molecular size; therefore, the study also
used the diffusion cell to evaluate the diffusivity of the SMP under various different chemical conditions
(pH, calcium concentration). The study also conducted a comparison of the mass transfer coefficient of the SMP
in terms of surface morphology of different NF membranes. Includes abstract only.