1.1 这些试验方法包括化学成分在以下范围内的碳钢、低合金钢、硅电工钢、钢锭和熟铁的化学分析: 要素 成分范围， % 铝 0.001 至1.50 锑 0.002 至0.03 砷 0.0005至0.10 铋 0.005 至0.50 硼 0.0005至0.02 钙 0.0005至0.01 铈 0.005 至0.50 铬 0.005 至3.99 钴 0.01  至0.30 铌 0.002 至0.20 铜 0.005 至1.50 镧 0.001 至0.30 领导 0.001 到0。 50 锰 0.01  至2.50 钼 0.002 至1.50 镍 0.005 至5.00 氮 0.0005至0.04 氧气 0.0001至0.03 磷 0.001 至0.25 硒 0.001 至0.50 硅 0.001 至5.00 硫黄 0.001 至0.60 锡 0.002 至0.10 钛 0.002 至0.60 钨 0.005 至0.10 钒 0.005 至0.50 锆 0.005 至0.15 1.2 本标准中的试验方法包含在以下章节中: 章节 铝，总量，通过8-喹啉重量法 方法（0.20 %至1.5 %) 124 – 131 铝，总计，按8- 喹啉 分光光度法 （0.003 %至0.20 %) 76 – 86 总铝或酸溶性铝，原子法 吸收 光谱法 （0.005 %至0.20 %) 308 – 317 锑的亮绿色分光光度法 方法（0.0002 %至0.030 %) 142 – 151 原子吸收光谱法测定铋 方法（0.02 %至0.25 %) 298 – 307 姜黄素蒸馏硼 分光光度法 （0.0003 %至0.006 %) 208 – 219 直流等离子体原子的钙 发射光谱法 （0.0005 %至0.010 %) 289 – 297 燃烧重量法测定的总碳 （0.05 %至1.80 %)— 1995年停产 用直流等离子体研究铈和镧 原子发射光谱法 （0.003 %至0.50 %铈，0.001 %至0.30 % 镧） 249 – 257 原子吸收光谱法测定铬 方法（0.006 %至1.00 %) 220 – 229 过硫酸根氧化滴定法测定铬 方法（0.05 %至3.99 %) 230 – 238 钴的亚硝基-R盐分光光度法 方法（0.01 %至0.30 %) 53 – 62 硫化物沉淀铜- 碘量计 滴定法( 1989年停产 ) 87 – 94 原子吸收光谱法测定铜 方法（0.004 %至0.5 %) 279 – 288 铜的新铜分光光度法 方法（0.005 %至1.50 %) 114 – 123 铅的离子交换——原子吸收 光谱法 （0.001 %至0.50 %) 132 – 141 原子吸收光谱法测定锰 方法（0.005 %至2.0 %) 269 – 278 高碘酸盐分光光度法测定锰 方法（0.01 %至2.5 %) 9 – 18 过硫酸亚砷酸盐滴定法测定锰 方法（0.10 %至2.50 %) 164 – 171 硫氰酸盐分光光度法测定钼 方法（0.01 %至1.50 %) 152 – 163 镍的原子吸收光谱法 方法（0.003 %至0.5 %) 318 – 327 镍的丁二酮肟重量法 方法（0.1 %至5.00 %) 180 – 187 镍的离子交换原子吸收 光谱法 （0.005 %至1.00 %) 188 – 197 蒸馏分光光度法测定氮 方法( 1988年停产 ) 63 – 75 碱度法测定磷 （0.02 %至0.25 %) 172 – 179 钼蓝的磷 分光光度法 （0.003 %至0.09 %) 19 – 30 硅的钼蓝分光光度法 方法（0.01 %至0.06 %) 103 – 113 硅的重量滴定法 方法（0.05 %至3.5 %) 46 – 52 重量法测定硫 ( 1988年停产 ) 31 – 36 燃烧碘酸盐滴定法测定硫 （0.005 %至0.3 %)( 2017年停产 ) 37 – 45 锡的硫化物沉淀碘量滴定法 方法（0.01 %至0.1 %) 95 – 102 锡的溶剂萃取原子吸收法 光谱法 （0.002 %至0.10 %) 198 – 207 二安替吡啉甲烷制钛 分光光度法 （0.025 %至0.30 %) 258 – 268 钒的原子吸收光谱法 方法（0.006 %至0.15 %) 239 – 248 1.3 测定本标准中未包含的几种元素的试验方法见《试验方法》 E1019 。 1.4 中给出的一些组成范围 1.1 过于宽泛，无法用单一的测试方法涵盖，因此本标准包含某些元素的多种测试方法。 用户必须通过将每种测试方法的范围和干扰部分中给出的信息与待分析合金的成分相匹配来选择合适的测试方法。 1.5 以国际单位制表示的数值应视为标准。在某些情况下，允许的例外情况 IEEE/ASTM SI 10 也被使用。 1.6 本标准并不旨在解决与其使用相关的所有安全问题（如有）。本标准的使用者有责任在使用前制定适当的安全、健康和环境实践，并确定监管限制的适用性。 具体危害说明见第节 6. 以及在这些试验方法的特殊“警告”段落中。 1.7 本国际标准是根据世界贸易组织技术性贸易壁垒委员会发布的《关于制定国际标准、指南和建议的原则的决定》中确立的国际公认的标准化原则制定的。 ====意义和用途====== 4.1 这些用于金属和合金化学分析的试验方法主要用于试验此类材料是否符合成分规范，特别是ASTM委员会A01钢、不锈钢和相关合金委员会和A04铁铸件委员会管辖的材料。 假设所有使用这些测试方法的人员都是经过培训的分析员，能够熟练、安全地执行常见的实验室程序。预计工作将在适当的质量控制实践（如指南中所述）下，在设备齐全的实验室中进行 E882 。

1.1 These test methods cover the chemical analysis of carbon steels, low-alloy steels, silicon electrical steels, ingot iron, and wrought iron having chemical compositions within the following limits: Element Composition Range, % Aluminum 0.001  to 1.50 Antimony 0.002  to 0.03 Arsenic 0.0005 to 0.10 Bismuth 0.005  to 0.50 Boron 0.0005 to 0.02 Calcium 0.0005 to 0.01 Cerium 0.005  to 0.50 Chromium 0.005  to 3.99 Cobalt 0.01   to 0.30 Columbium (Niobium) 0.002  to 0.20 Copper 0.005  to 1.50 Lanthanum 0.001  to 0.30 Lead 0.001  to 0.50 Manganese 0.01   to 2.50 Molybdenum 0.002  to 1.50 Nickel 0.005  to 5.00 Nitrogen 0.0005 to 0.04 Oxygen 0.0001 to 0.03 Phosphorus 0.001  to 0.25 Selenium 0.001  to 0.50 Silicon 0.001  to 5.00 Sulfur 0.001  to 0.60 Tin 0.002  to 0.10 Titanium 0.002  to 0.60 Tungsten 0.005  to 0.10 Vanadium 0.005  to 0.50 Zirconium 0.005  to 0.15 1.2 The test methods in this standard are contained in the sections indicated as follows: Sections Aluminum, Total, by the 8-Quinolinol Gravimetric Method (0.20 % to 1.5 %) 124 – 131 Aluminum, Total, by the 8-Quinolinol Spectrophotometric Method (0.003 % to 0.20 %) 76 – 86 Aluminum, Total or Acid-Soluble, by the Atomic Absorption Spectrometry Method (0.005 % to 0.20 %) 308 – 317 Antimony by the Brilliant Green Spectrophotometric Method (0.0002 % to 0.030 %) 142 – 151 Bismuth by the Atomic Absorption Spectrometry Method (0.02 % to 0.25 %) 298 – 307 Boron by the Distillation-Curcumin Spectrophotometric Method (0.0003 % to 0.006 %) 208 – 219 Calcium by the Direct-Current Plasma Atomic Emission Spectrometry Method (0.0005 % to 0.010 %) 289 – 297 Carbon, Total, by the Combustion Gravimetric Method (0.05 % to 1.80 %)— Discontinued 1995 Cerium and Lanthanum by the Direct Current Plasma Atomic Emission Spectrometry Method (0.003 % to 0.50 % Cerium, 0.001 % to 0.30 % Lanthanum) 249 – 257 Chromium by the Atomic Absorption Spectrometry Method (0.006 % to 1.00 %) 220 – 229 Chromium by the Peroxydisulfate Oxidation-Titration Method (0.05 % to 3.99 %) 230 – 238 Cobalt by the Nitroso-R Salt Spectrophotometric Method (0.01 % to 0.30 %) 53 – 62 Copper by the Sulfide Precipitation-Iodometric Titration Method ( Discontinued 1989 ) 87 – 94 Copper by the Atomic Absorption Spectrometry Method (0.004 % to 0.5 %) 279 – 288 Copper by the Neocuproine Spectrophotometric Method (0.005 % to 1.50 %) 114 – 123 Lead by the Ion-Exchange—Atomic Absorption Spectrometry Method (0.001 % to 0.50 %) 132 – 141 Manganese by the Atomic Absorption Spectrometry Method (0.005 % to 2.0 %) 269 – 278 Manganese by the Metaperiodate Spectrophotometric Method (0.01 % to 2.5 %) 9 – 18 Manganese by the Peroxydisulfate-Arsenite Titrimetric Method (0.10 % to 2.50 %) 164 – 171 Molybdenum by the Thiocyanate Spectrophotometric Method (0.01 % to 1.50 %) 152 – 163 Nickel by the Atomic Absorption Spectrometry Method (0.003 % to 0.5 %) 318 – 327 Nickel by the Dimethylglyoxime Gravimetric Method (0.1 % to 5.00 %) 180 – 187 Nickel by the Ion-Exchange-Atomic-Absorption Spectrometry Method (0.005 % to 1.00 %) 188 – 197 Nitrogen by the Distillation-Spectrophotometric Method ( Discontinued 1988 ) 63 – 75 Phosphorus by the Alkalimetric Method (0.02 % to 0.25 %) 172 – 179 Phosphorus by the Molybdenum Blue Spectrophotometric Method (0.003 % to 0.09 %) 19 – 30 Silicon by the Molybdenum Blue Spectrophotometric Method (0.01 % to 0.06 %) 103 – 113 Silicon by the Gravimetric Titration Method (0.05 % to 3.5 %) 46 – 52 Sulfur by the Gravimetric Method ( Discontinued 1988 ) 31 – 36 Sulfur by the Combustion-Iodate Titration Method (0.005 % to 0.3 %) ( Discontinued 2017 ) 37 – 45 Tin by the Sulfide Precipitation-Iodometric Titration Method (0.01 % to 0.1 %) 95 – 102 Tin by the Solvent Extraction-Atomic Absorption Spectrometry Method (0.002 % to 0.10 %) 198 – 207 Titanium by the Diantipyrylmethane Spectrophotometric Method (0.025 % to 0.30 %) 258 – 268 Vanadium by the Atomic Absorption Spectrometry Method (0.006 % to 0.15 %) 239 – 248 1.3 Test methods for the determination of several elements not included in this standard can be found in Test Methods E1019 . 1.4 Some of the composition ranges given in 1.1 are too broad to be covered by a single test method and therefore this standard contains multiple test methods for some elements. The user must select the proper test method by matching the information given in the Scope and Interference sections of each test method with the composition of the alloy to be analyzed. 1.5 The values stated in SI units are to be regarded as standard. In some cases, exceptions allowed in IEEE/ASTM SI 10 are also used. 1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 6 and in special “Warning” paragraphs throughout these test methods. 1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee. ====== Significance And Use ====== 4.1 These test methods for the chemical analysis of metals and alloys are primarily intended as referee methods to test such materials for compliance with compositional specifications, particularly those under the jurisdiction of ASTM Committees A01 on Steel, Stainless Steel, and Related Alloys and A04 on Iron Castings. It is assumed that all who use these test methods will be trained analysts capable of performing common laboratory procedures skillfully and safely. It is expected that work will be performed in a properly equipped laboratory under appropriate quality control practices such as those described in Guide E882 .