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Application of a Novel Oxidant-Coagulant for Arsenic Removal in Drinking Water Treatment 新型氧化混凝剂在饮用水除砷中的应用
发布日期: 2005-11-01
本研究的目的是建立一个技术和经济比较的传统方法 饮用水中砷去除的现有和创新处理方法。这项工作显示了人们的兴趣 一种基于高铁酸盐强化脱砷的新技术。 高铁酸盐(VI)离子(分子式FeO4 2-)是一种非常强的氧化剂,在酸性条件下具有 氧化还原电位大于臭氧和通常用于水的其他主要氧化剂/消毒剂的氧化还原电位 治疗此外,由于在所有氧化反应中生成的铁离子形成氢氧化物低聚物, 凝血最终会发生。因此,高铁酸盐(VI)代表了一种双重性质- 功能(氧化剂和凝固剂) 化学试剂,可有效替代目前的饮用水和饮用水处理方法 废水处理。 在欧洲共同体第五框架部分资助的研究和示范项目中 该项目由九个欧洲合作伙伴组成,目前正在开发高铁酸盐的优化方法 大规模生产和研究高铁酸盐在工业、城市废物或环境中的几种应用 饮用水处理。因此,改进现有的处理工艺和评估 需要高铁酸盐等新技术来遵守新规定。在这个项目中, 关于高铁酸钾用于城市水处理的实验室规模试验已经完成 开展。 在实验室规模上进行了脱砷优化(罐试验、氧化和过滤试验) 在受砷和锰污染的天然地下水上进行。进行了以下治疗: 比较和优化: 使用混凝剂FeCl3和KMnO4; 使用新化学品(高铁酸盐);和 使用FeCl3和高铁酸盐的组合。 根据去除砷的效率对不同处理工艺进行分类, 获得了锰和铁。确定了最佳操作条件和化学药剂用量 确定,针对每个处理过程。 由于对砷的新规定,饮用水供应商需要评估具体的工艺,以 清除这种污染物。有几种有效的治疗方法。具有双重功能的高铁酸盐(VI) (氧化剂和凝固剂)是一种有效的化学品,有望替代传统的 饮用水生产中砷和锰的去除方法。包括参考资料、表格、图表。
The objectives of this study are to establish a technical and economical comparison of conventional existing and innovative treatments for Arsenic removal in drinking water. The work shows the interest of a new technology based on the use of ferrate for enhanced Arsenic removal. Ferrate(VI) ion (molecular formula FeO4 2-) is a very strong oxidant, which under acidic conditions, has a redox potential greater than that of ozone and of other main oxidants/disinfectants typically used for water treatment. Also, since the ferric ion generated in all oxidation reactions forms hydroxide oligomers, coagulation occurs eventually. Hence, ferrate(VI) represents a dual-function (oxidant and coagulant) chemical reagent that can be an effective alternative to current approaches for drinking water and wastewater treatment. Within a research and demonstration project partially funded by the European Community 5th Framework Program, a consortium of nine European partners, is currently developing optimized methods for ferrate production on a large scale and studying several applications of ferrate in industrial, urban waste or drinking water treatment. Consequently, improvement of existing treatment processes and evaluation of new technologies such as Ferrate are needed to comply with the new regulation. Within this project, laboratory scale tests concerning the use of potassium ferrate for municipal water treatment have been carried out. Arsenic removal optimization was conducted on bench scale (Jar test, oxidation and filtration tests) performed on natural groundwater polluted by arsenic and manganese. The following treatments were compared and optimized: use of coagulant FeCl3 and KMnO4; use of new chemical (ferrate); and, use of combination of FeCl3 and ferrate. A classification of the different treatment processes according to their efficiency to remove arsenic, manganese and iron has been obtained. The optimal operating conditions and chemical dosage have been determined, for each treatment process. Because of the new regulation on arsenic, drinking water suppliers need to assess specific processes to remove this pollutant. Several efficient treatments are available. Ferrate(VI) having a dual-function (oxidant and coagulant) can be an effective chemical and promising alternative to conventional approaches for arsenic and manganese removal in drinking water production. Includes references, tables, figures.
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发布单位或类别: 美国-美国给水工程协会
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