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Standard Practice for Optimization, Calibration, and Validation of Atomic Absorption Spectrometry for Metal Analysis of Petroleum Products and Lubricants 石油产品和润滑剂金属分析的原子吸收光谱法优化 校准和验证标准实践
发布日期: 2020-07-01
1.1 本规程涵盖了使用原子吸收光谱法(AAS)进行元素测量的校准和操作指南信息。 1.1.1 AAS相关标准- 试验方法 D1318 , D3237 , D3340 , D3605 , D3831 , D4628 , D5056 , D5184 , D5863 , D6732 ; 实践 D7260 和 D7455 ; 和试验方法 D7622 和 D7623 . 1.2 以国际单位制表示的数值应视为标准值。本标准不包括其他计量单位。 1.3 本标准并非旨在解决与其使用相关的所有安全问题(如有)。本标准的用户有责任在使用前制定适当的安全、健康和环境实践,并确定监管限制的适用性。 1.4 本国际标准是根据世界贸易组织技术性贸易壁垒(TBT)委员会发布的《关于制定国际标准、指南和建议的原则的决定》中确立的国际公认标准化原则制定的。 ====意义和用途====== 5.1 对石油产品和润滑剂进行准确的元素分析是确定化学性质的必要条件,化学性质用于确定是否符合商业和监管规范。 5.2 原子吸收光谱法(AAS)是石油工业中最广泛使用的元素分析技术之一。 ASTM D02石油产品和润滑剂委员会发布了至少12种标准试验方法用于此类分析。看见 表1 . 5.3 使用原子吸收光谱分析的优点包括对大多数金属具有良好的灵敏度,相对不受干扰,以及能够根据元素标准校准仪器,而不管其元素化学形式如何。因此,该技术已成为大多数石油工业实验室的选择方法。在许多实验室中,原子吸收光谱已被优越的ICP-AES技术所取代(见实践) D7260 ). 5.4 其他标准编写机构也发布了一些ASTM AAS标准测试方法,作为技术等效标准。 看见 表2 . (A) 摘自ASTM MNL44, ASTM石油产品和润滑剂分析试验方法指南 ,第2版,编辑,Nadkarni,R.A.Kishore,ASTM国际,宾夕法尼亚州西康舍霍肯,2007年。
1.1 This practice covers information on the calibration and operational guidance for elemental measurements using atomic absorption spectrometry (AAS). 1.1.1 AAS Related Standards— Test Methods D1318 , D3237 , D3340 , D3605 , D3831 , D4628 , D5056 , D5184 , D5863 , D6732 ; Practices D7260 and D7455 ; and Test Methods D7622 and D7623 . 1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee. ====== Significance And Use ====== 5.1 Accurate elemental analysis of petroleum products and lubricants is necessary for the determination of chemical properties, which are used to establish compliance with commercial and regulatory specifications. 5.2 Atomic Absorption Spectrometry (AAS) is one of the most widely used analytical techniques in the oil industry for elemental analysis. There are at least twelve Standard Test Methods published by ASTM D02 Committee on Petroleum Products and Lubricants for such analysis. See Table 1 . 5.3 The advantage of using an AAS analysis include good sensitivity for most metals, relative freedom from interferences, and ability to calibrate the instrument based on elemental standards irrespective of their elemental chemical forms. Thus, the technique has been a method of choice in most of the oil industry laboratories. In many laboratories, AAS has been superseded by a superior ICP-AES technique (see Practice D7260 ). 5.4 Some of the ASTM AAS Standard Test Methods have also been issued by other standard writing bodies as technically equivalent standards. See Table 2 . (A) Excerpted from ASTM MNL44, Guide to ASTM Test Methods for the Analysis of Petroleum Products and Lubricants , 2nd edition, Ed., Nadkarni, R. A. Kishore, ASTM International, West Conshohocken, PA, 2007.
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归口单位: D02.03
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