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Standard Guide for Using Fourier Transform Infrared Spectrometry to Evaluate Synthetic Equine Surface Components 用傅里叶变换红外光谱法评定合成马表面成分的标准指南
发布日期: 2021-04-15
1.1 涉及红外显微镜的红外(IR)分光光度法与傅立叶变换红外(FTIR)光谱仪相结合,是识别合成马表面使用的聚合物纤维(即聚丙烯、聚乙烯等)和橡胶的一种有价值的方法。FTIR还可用于识别从马表面提取的粘合剂(即高油蜡)中存在的有机化合物和其他非金属元素。蜡基粘合剂的FTIR也可以检测和量化粘合剂氧化的相对程度。FTIR的工作原理是检测和解释分子结构中结合在一起的原子的振荡。从测试样品中生成红外光吸收光谱,并将这些光谱与已知聚合物光谱库进行比较。对于大块纤维样品,将不同的纤维目视分为几组,并对每组中的单个纤维进行测试。 对于提取的蜡,进行了多次测试以确保一致性。两种常见纤维的FTIR吸收光谱如所示 图1 . 显示氧化峰的蜡粘合剂的FTIR光谱如所示 图2 . 1.2 以国际单位制表示的数值应视为标准值。本标准不包括其他计量单位。 图1 大块纤维中聚合物类型的FTIR识别 图2 多年来蜡粘合剂中的氧化活性(注意氧化峰值在1700厘米左右 –1 (1)) 1.3 本标准并非旨在解决与其使用相关的所有安全问题(如有)。本标准的用户有责任在使用前制定适当的安全、健康和环境实践,并确定监管限制的适用性。 1.4 本国际标准是根据世界贸易组织技术性贸易壁垒(TBT)委员会发布的《关于制定国际标准、指南和建议的原则的决定》中确立的国际公认标准化原则制定的。 ====意义和用途====== 5.1 FTIR可以快速用于识别聚合物纤维和一些无机材料。FTIR除了观察氧化外,还提供了一种监测马表面粘合剂材料变化的方法。
1.1 Infrared (IR) spectrophotometry involving IR microscopes, coupled with Fourier transform infrared (FTIR) spectrometers, is a valuable method of identifying polymeric fibers (that is, polypropylene, polyethylene, etc.) and rubber used in synthetic equine surfaces. FTIR may also be used to identify organic compounds and other non-metallic elements present in the binder (that is, high-oil wax) extracted from an equine surface. FTIR of wax-based binders can also detect and quantify relative degrees of binder oxidation. FTIR works by detecting and interpreting the oscillations of the atoms bonded together in the molecular structure. Infrared light absorption spectra are generated from samples tested, and these spectra are compared to libraries of known polymer spectra. For bulk fiber samples, different fibers are visually separated into groups and individual fibers from each group are tested. For extracted wax, several tests are conducted to ensure consistency. FTIR absorption spectrums for two common fibers are shown in Fig. 1 . FTIR spectrum for a wax binder exhibiting oxidation peaks is shown in Fig. 2 . 1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. FIG. 1 FTIR Identification of Polymer Types in Bulk Fiber FIG. 2 Oxidation Activity in Wax Binder over Multiple Years (Note Oxidation Peak at ~1700 cm –1 (1)) 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee. ====== Significance And Use ====== 5.1 FTIR can quickly be utilized to help identify polymeric fibers and some inorganic materials. FTIR also provides a means of monitoring changes to equine surface binder materials, in addition to observing oxidation.
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归口单位: F08.28
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