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现行 ISO 23484:2023
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Determination of particle concentration by small-angle X-ray scattering (SAXS) 小角度X射线散射法测定颗粒浓度
发布日期: 2023-07-05
本文介绍了小角X射线散射(SAXS)在测量悬浮液中颗粒浓度中的应用。在该文献中,仅处理足够单分散的球形颗粒的浓度,这意味着尺寸分布的宽度通常低于约50?平均直径的%。这里,微分散射截面可以基于形状因子来计算,形状因子仅取决于动量传递q和粒子半径r。此外,本文档仅限于稀释系统。SAXS意义上的稀释系统意味着不存在粒子相互作用。在长程相互作用(粒子之间的库仑力)的情况下,需要特别小心,并且可能需要降低浓度。

This document deals with the application of small-angle X-ray scattering (SAXS) for the measurement of the particle concentration in suspensions. In this document, only the concentration of sufficiently monodisperse spherical particles is treated, which means that the width of the size distribution is typically below about 50?% of the mean diameter. Here, the differential scattering cross section can be calculated based on the form factor, which depends only on the momentum transfer q and the particle radius r. Furthermore, this document is limited to dilute systems. A dilute system in the sense of SAXS means that particle interactions are absent. In case of long-range interactions (Coulomb forces between the particles), special care needs to be taken and a reduction of the concentration can be necessary.

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归口单位: ISO/TC 24/SC 4
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