Standard Practice for Evaluation of Methods for Determination of Kinetic Parameters by Calorimetry and Differential Scanning Calorimetry
通过量热法和差示扫描量热法测定动力学参数的方法的标准实践
1.1
The purpose of this practice is to provide kinetic parameters for reference materials used to evaluate thermal analysis methods, apparatus, and software where enthalpy and temperature are measured. This practice addresses both exothermic and endothermic,
n
th
order, and autocatalytic reactions.
1.2
The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3
This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4
This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
====== Significance And Use ======
5.1
The kinetic parameters provided in this practice may be used to evaluate the performance of a standard, apparatus, technique, or software for the determination parameters (such as Test Methods
E698
,
E1641
,
E2041
, or
E2070
) using thermal analysis techniques such as differential scanning calorimetry, and accelerating rate calorimetry (Guide
E1981
). The results obtained may be compared to the values provided by this practice.
Note 4:
Not all reference materials are suitable for each measurement technique.