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现行 ISO 10702:1993
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Steel and iron — Determination of nitrogen content — Titrimetric method after distillation 钢铁及粉煤灰;氮含量的测定——蒸馏后滴定法
发布日期: 1993-06-24
规定方法的原理是将试验部分溶解在盐酸中,然后用过氧化氢氧化,用硫酸钾和硫酸铜(II)熏制酸不溶性残留物,用氢氧化钠蒸馏成碱性的溶液,在含有原硼酸溶液的接收器中收集氨,用氨基磺酸滴定铵离子。适用于从0002%(m/m)到0.5%(m/m)的氮含量;不适用于含有氮化硅的样品。
The principle of the method specified is dissolving a test portion in hydrochloric acid followed by oxidation with hydrogen peroxide, fuming of the acid-insoluble residue in sulfuric acid with potassium sulfate and copper(II) sulfate, distilling the solution made alkaline with sodium hydroxide, collecting ammonia in a receiver containing orthoboric acid solution, titration of the ammonium ion with amidosulfuric acid. Is applicable to nitrogen contents from 0,002 % (m/m) to 0,5 % (m/m); does not apply to samples containing silicon nitride.
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归口单位: ISO/TC 17/SC 1
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