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Analysis of Metals by Inductively Coupled Plasma-Mass Spectrometry: Effect of Concentration on Accuracy and Precision 电感耦合等离子体质谱法分析金属:浓度对准确度和精密度的影响
发布日期: 1998-01-01
本文描述了电感耦合等离子体质谱仪(ICP-MS)的实施和优点,并提供了有关峰浓度对选定测定的精密度和准确度影响的数据。本文的实验部分考察了分析物浓度对分析方法某些质量特性的影响。进行的实验中,测定的准确度和精密度作为峰浓度的函数进行评估。然后以高于或低于先前计算的MDL的浓度制备标准溶液。这些实验的目的是确定在不同的加标浓度下,回收率和相对标准偏差百分比(RSD)是如何变化的。
This paper describes the implementation and benefits of an Inductively Coupled Plasma-Mass Spectrometer (ICP-MS) and presents data on the effect of spike concentration on precision and accuracy of selected determinations. The experimental section of this paper examines the effect of analyte concentration on some quality characteristics of analytical methods. Experiments were conducted in which the accuracy and precision of determinations were assessed as a function of spike concentration. Standard solutions were then prepared at concentrations above and below previously calculated MDLs. The objectives of these experiments were to determine how % Recovery and % Relative Standard Deviation (RSD) varied at different spike concentrations.
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发布单位或类别: 美国-美国给水工程协会
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