Styrene-butadiene rubber (SBR). Determination of the microstructure of solution-polymerized SBR-<sup>1</sup>H-NMR and IR with cast-film method
丁苯橡胶(SBR) 溶聚丁苯橡胶微观结构的测定
发布日期:
2015-07-31
BS ISO 21561-1:2015规定了混凝土微观结构的定量测定程序
1H-NMR法测定溶聚丁苯橡胶(S-SBR)中丁二烯和苯乙烯的含量
作为绝对方法,红外光谱法作为相对方法。苯乙烯含量表示为:
相对于整个聚合物的质量百分比。反式、顺式和乙烯基含量以相对摩尔百分比表示
去丁二烯。这些方法仅适用于生橡胶。注1:红外光谱法还可以通过使用已知的S-SBRs进行校准,给出微观结构的绝对值
通过1H-NMR光谱获得的绝对微观结构。注2:ISO 21561本部分仅使用“乙烯基”、“反式”和“顺式”。然而,乙烯基的表达,
反式和顺式的意思一般如下:乙烯基:乙烯基单元,乙烯基键,1,2-
单元、1,2-键、1,2-乙烯基单元或1,2-乙烯基键;反式:1,4-反式单元、1,4-反式键、反式1,4单元或反式1,4键;顺式:1,4-顺式单元、1,4-顺式键、顺式1,4单元或顺式1,4键。交叉引用:ISO 1407ISO 1795ISO/TR 9272取代BS ISO 21561:2005+A1:2010,该标准仍然有效。购买本文件时,所有当前可用的修订版均包含在购买本文件中。
BS ISO 21561-1:2015 specifies procedures for the quantitative determination of the microstructure of
the butadiene and the content of styrene in solution-polymerized SBR (S-SBR) by 1H-NMR spectrometry
as an absolute method and by IR spectrometry as a relative method. The styrene content is expressed in
mass % relative to the whole polymer. The trans, cis and vinyl contents are expressed in mol % relative
to the butadiene. These methods are applicable only for raw rubber.NOTE 1 IR spectrometry can also give absolute values of microstructure by calibration with S-SBRs of known
absolute microstructure obtained by 1H-NMR spectrometry.NOTE 2 Only "vinyl", "trans" and "cis" are used in this part of ISO 21561. However, the expression of vinyl,
trans and cis mean as follows in general:vinyl: vinyl unit, vinyl bond, 1,2-unit, 1,2-bond, 1,2-vinyl-unit or 1,2-vinyl-bond;trans: 1,4-trans unit, 1,4-trans bond, trans-1,4 unit or trans1,4 bond;cis: 1,4-cis unit, 1,4-cis bond, cis-1,4 unit or cis-1,4 bond.Cross References:ISO 1407ISO 1795ISO/TR 9272Replaces BS ISO 21561:2005+A1:2010 which remains currentAll current amendments available at time of purchase are included with the purchase of this document.