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Going Beyond Iodine Number and BET Surface Area - Suggestions for Selecting Activated Carbons Based on Pore Structure and Surface Chemistry 超越碘数和BET表面积——基于孔结构和表面化学选择活性炭的建议
发布日期: 2002-06-16
本研究的目的是通过以下方法探索替代活性炭的选择标准: 测定活性炭孔结构和表面化学对表面活性的影响 相对极性(甲基叔丁基醚[MTBE])和相对非极性 (三氯乙烯[TCE])天然有机物存在下的痕量有机化合物 (名称)。系统研究活性炭孔结构和表面活性的影响 研究了活性炭纤维(ACF)基质的吸附化学。ACF 基质包含3个活化水平和4个表面化学水平(酸洗、氧化、, 氢处理,氨处理)。此外,3种商用颗粒活性炭 对炭(GAC)进行了研究[coal-based Filtrasorb 600(Calgon Carbon Corp.),椰子壳- 基于G219(PicaUSA)和wood- 基于Picazine(PicaUSA)]。物理化学吸附剂 表征包括通过超低压N2测定孔结构和表面积 吸附、零电荷点(PZC)测定、红外光谱和元素分析 分析。在超纯水和水中收集了MTBE和TCE的吸附等温线数据 圣华金三角洲水域(SJDW,康科德,加利福尼亚州)。ACF基质的材料和方法 详细描述了制备、吸附剂表征和等温线实验。包括3个参考文献、表格和图表。
The objective of this research was to explore alternative activated carbon selection criteria by determining the effects of activated carbon pore structure and surface chemistry on the adsorption of a relatively polar (methyl tertiary-butyl ether [MTBE]) and a relatively nonpolar (trichloroethene [TCE]) trace organic compound in the presence of natural organic matter (NOM). To systematically study the effects of activated carbon pore structure and surface chemistry on adsorption, a matrix of activated carbon fibers (ACFs) was examined. The ACF matrix contained 3 activation levels and 4 surface chemistry levels (acid-washed, oxidized, hydrogen-treated, ammonia-treated). In addition, 3 commercially available granular activated carbons (GACs) were studied [coal-based Filtrasorb 600 (Calgon Carbon Corp.), coconut shell- based G219 (PicaUSA), and wood-based Picazine (PicaUSA)]. Physical and chemical adsorbent characterization included pore structure and surface area determinations by ultra-low pressure N2 adsorption, point of zero charge (PZC) determinations, infrared spectroscopy, and elemental analyses. Adsorption isotherm data for MTBE and TCE were collected in ultrapure water and in San Joaquin Delta Water (SJDW, Concord, CA). Materials and methods for ACF matrix preparation, adsorbent characterization, and isotherm experiments have been described in detail. Includes 3 references, tables, figures.
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发布单位或类别: 美国-美国给水工程协会
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