Despite the documented inefficacy of the calcium
carbonate approach to corrosion control,
adjustment of calcium carbonate remains the
dominant corrosion control strategy. Many utilities
still significantly increase alkalinity (with
limited or no success) or try to operate at much
lower pH values than necessary, both as a
means of lead and copper control.
Consistent high pH is the main variable
controlling release of lead and copper at customer
taps. The extent to which pH can be
raised must be carefully evaluated on the basis
of site-specific conditions. The San Francisco
Public Utilities Commission (SFPUC) case
profiled here demonstrates that maintaining a
high pH is a more appropriate corrosion control
treatment to comply with the Lead and
Copper Rule (LCR) than adjusting the
Langelier saturation index or augmenting
alkalinity. The combination of water quality
and distribution system conditions at SFPUC
is such that a switch from free chlorine to
chloramine did not affect lead and copper
release or LCR compliance. Includes 49 references, tables, figures.