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Comparing Adsorption of Organic Contaminants by Carbon Nanotubes, Activated Carbons, and Activated Carbon Fiber 碳纳米管、活性炭和活性炭纤维对有机污染物吸附的比较
发布日期: 2009-11-01
三种单壁吸附剂对两种合成有机化合物的吸附 对不同水质条件下的碳纳米管进行了系统研究 条件为了进行比较,使用了微孔活性炭纤维(ACF10)和双峰多孔炭纤维 具有类似表面化学性质的颗粒活性炭(HD4000)也被用于该试验 工作实验结果表明,SOC和NOM之间的竞争会加剧 与水具有相似表面亲和力的吸附剂的种类不受表面积或孔隙的控制 体积,但受其孔径分布控制。两者都是吸附的直接竞争 在SOCs的吸附过程中发生了NOM的位置和孔隙堵塞。对于微孔 ACF10,由于小微孔对NOM大分子不易接近,因此 堵塞在竞争中占主导地位,而对于双峰介孔HD4000,直接 场地竞争占主导地位,导致SOC吸收和表面异质性降低 吸附剂。与ACF10和HD4000相比,NOM预加载和 单壁碳纳米管上的同时吸附要弱得多,这意味着一旦释放到自然环境中 在水体中,单壁碳纳米管会吸附大量有毒的有机碳,并将其转移到其他水体中 系统通过纳米管的运输。与NOM效应相比,NOM效应 研究了离子强度和溶液pH值对SOCs在单壁碳纳米管上吸附的影响 微不足道的包括19个参考文献、表格和图表。
Adsorption of two synthetic organic compounds (SOCs) by three single-walled carbon nanotubes (SWNTs) was systematically studied under different water quality conditions. For comparison, a microporous activated carbon fiber (ACF10) and a bimodal porous granular activated carbon (HD4000) with similar surface chemistry were also employed in this work. Experimental results demonstrate that the competition between SOCs and NOM uptakes of adsorbents with similar surface affinity to water was not controlled by surface area or pore volume but controlled by their pore size distributions. Both direct competition for adsorption sites and pore blockage by NOM occurred in the adsorption of SOCs. For the microporous ACF10, due to the inaccessibility of the small micropores to NOM macromolecules, pore blockage predominated in the competition, whereas for the bimodal mesoporous HD4000, direct site competition dominated, which led to a reduction in SOC uptake and in surface heterogeneity of the adsorbent. Compared with ACF10 and HD4000, the effects of NOM preloading and simultaneous adsorption on SWNTs were much weaker, implying that once released into natural water body, SWNTs will adsorb a considerable amount of toxic SOCs and transfer them to other systems by the transportation of the nanotubes. Compared with the effect of NOM, the effects of ionic strength and pH of the bulk solution on the adsorption of SOCs on SWNTs were insignificant. Includes 19 references, tables, figure.
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发布单位或类别: 美国-美国给水工程协会
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