Floc breakage during particle-liquid separation can lead to significant operational problems, such as
reduced clarification rates and filter run times. For natural organic matter (NOM) removal using
conventional coagulation, previous research has shown that improved floc properties may be seen
when the ratio of organics to coagulant is reduced. However, that implies the addition of higher
coagulant doses leading to increased sludge production. Water pretreatment with a magnetic ion
exchange resin (MIEX®) followed by conventional coagulation can reduce the coagulant dose by up to
80 % without negatively affecting the level of NOM removal. However, the impact of MIEX® pretreatment
and reduced coagulant dose on floc particles has not yet been fully investigated. Results have
shown that MIEX is able to significantly reduce the charge concentration in organic rich waters.
Logically this reduction, was thought to be the reason, for the potential coagulant dose reduction. It is
known that the charge of the anionic organics has to be neutralized in order to remove it effectively by
precipitation.
Further on it was shown in this study that NOM character was important in determining how the floc
physical properties were affected by MIEX® pretreatment. A significant increase in floc size, strength
and settling velocity was measured for coagulated NOM after MIEX® pretreatment, in comparison to
conventional coagulation for waters dominated by hydrophobic compounds. Treatment of hydrophilic
waters did not result in such significant improvement of floc physical properties. Considering these
results, MIEX® looks capable of engineering robust downstream floc particles for selected waters,
while also reducing potential sludge production by applying very low coagulant doses.
Includes 38 references, table, figures.