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The Formation and Fate of Disinfection Byproducts During Coagulation with Chlorine and Chlorine Dioxide Preoxidation 氯气和二氧化氯预氧化混凝过程中消毒副产物的形成和去向
发布日期: 2004-11-15
本研究的目的是了解消毒副产物(DBP)与天然有机物(NOM)的相互作用 常规处理过程中的絮状物,重点是 DBP,并表征和量化在氯和 二氧化氯预氧化剂应用。使用实验室规模的震击器测试装置来模拟全尺寸的常规震击器 处理过程。在所有实验中都使用了一种改进的有限顶空罐来 最小化易失性DBP的损失。试验在20℃±1℃下用铝进行 硫酸盐(Al2(SO43·14H2O,明矾)作为混凝剂,并对其进行了初步试验 选择所需的明矾剂量,以满足美国环境保护局(USEPA)的强化混凝总有机碳(TOC)去除要求 要求。进行罐试验,以模拟快速混合、锥形 絮凝和沉淀。该研究计划利用了四个水域。选择源水 来自美国不同的地理位置,包括各种原料 水质,如浊度和通过总有机碳测量的NOM浓度 (TOC)。明矾的投料浓度为20 g/L,由Fisher Scientific公司制备 认证等级硫酸铝。研究中使用的氧化剂取自 以下储备溶液:氯3675 mg/L;二氧化氯2000毫克/升, 在科罗拉多州柯林斯堡科罗拉多州立大学现场生成。可吸附有机卤素(AOX)测量是使用 三菱TOX-10型,采用改进的标准方法5320B。三氯甲烷 (THMs)和卤乙酸(HAAs)使用HP GC 6890进行分析 分别为修改后的美国环保局方法551.1和修改后的标准方法6251 B。实验方法包括氯、天然有机物、絮体和混凝过程中消毒副产物的相互作用。包括3个参考文献、表格和图。
The objectives of this study are to understand the interactions of disinfection byproducts (DBPs) with natural organic matter (NOM) and flocs during conventional treatment, focusing on the solid / liquid phase formation of DBPs, and to characterize and quantify the extent of DBPs that form under chlorine and chlorine dioxide preoxidant application. A bench-scale jar testing apparatus was used to simulate the full-scale conventional treatment process. A modified jar with limited headspace was used in all experiments to minimize the loss of volatile DBPs. Tests were conducted at 20°C ± 1°C with aluminum sulfate (Al2(SO4)3 · 14H2O, alum) as the coagulant, and preliminary tests were performed to select the alum dose needed to meet US Environmental Protection Agency's (USEPA) enhanced coagulation total organic carbon (TOC) removal requirements. Jar tests were run to simulate rapid mix, tapered flocculation and sedimentation. This research plan utilized four waters. The source waters were selected from distinct geographical locations within the United States to encompass a spectrum of raw water quality, such as turbidity and NOM concentration as measured by total organic carbon (TOC). Alum was dosed from a stock concentration of 20 g/L prepared from Fisher Scientific certified grade aluminum sulfate. The oxidants that were used in the study were taken from the following stock solutions: chlorine 3675 mg/L; and, chlorine dioxide 2000 mg/L, generated on site at Colorado State University, Fort Collins, Colorado. Adsorbable organic halogens (AOX) measurements were conducted using a Mitsubishi model TOX-10 using a modified Standard Method 5320B. Trihalomethanes (THMs) and haloacetic acids (HAAs) were analyzed using a HP GC 6890 applying a modified USEPA Method 551.1 and a modified Standard Method 6251 B, respectively. The experimental approach included chlorine, natural organic matter, floc and disinfection byproduct interactions during coagulation. Includes 3 references, tables, figures.
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发布单位或类别: 美国-美国给水工程协会
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