While most water treatment facilities are most concerned with the finished water quality
produced, reverse osmosis (RO) facilities are also concerned with the quality of their
concentrate. The City of Vero Beach, Florida has successfully operated their RO facility
for the past 11 years with the originally installed membrane elements. In recent years,
membrane performance has decreased and feed pressures have increased significantly.
Chemically cleaning the elements provided an effective short-term solution to the
performance problems; however, the membranes returned to their pre-cleaning condition
in less than three months. Based upon the rapid decline in the membrane performance
and age of the membranes, the City elected to replace the membrane elements. Three
manufacturers of 8-1/2 inch thin film composite membranes were tested side by side on
the identical feed water quality. The design of the membrane skid allows for a full-scale
demonstration of seven 8-1/2 inch membrane elements to be loaded into full-length
pressure vessels. The full-scale test evaluated both the physical operating parameters and
water quality produced from the condition feedwater, permeate, and concentrate stream.
This paper focuses on the concentrate water quality produced by the three membranes
tested. The City of Vero Beach currently disposes of concentrate water from the RO
facility into the Main Canal downstream of a tidal salinity barrier. The quality of the
concentrate water is critical in maintaining this method of disposal for this facility. The
current regulatory permit for the National Pollutant Discharge Elimination System
(NPDES) for their concentrate is discussed and compared to the data collected
during the demonstration pilot test. Membrane performance is evaluated based upon
meeting the NPDES permit criteria. The membranes are compared based upon the
results of acute and chronic toxicity testing that were performed on the concentrate of
each individual element.
The concentrate has been analyzed for a variety of parameters ranging from acute toxicity
to ion concentrations. The final membrane selection is based not only on permeate
quality but also concentrate quality. Comparisons between membrane performance
focusing on permeate quality and concentrate quality is made. Includes 3 references, tables, figures.