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Rapid Small Scale Column Test (RSSCT) Approach for Predicting Arsenic Breakthrough from a Fixed Bed Adsorber Containing an Iron Oxide Media 快速小规模柱试验(RSSCT)方法预测含氧化铁介质的固定床吸附器中砷的穿透
发布日期: 2006-06-01
本幻灯片概述了一项研究 数学模型被用来缩小全尺寸吸附器的尺寸 进行快速小规模柱试验(RSSCT),并保持性能之间的完美相似性 吸附器。 优点包括: 突破曲线(BTC)可以在一小部分时间内获得 时间 BTC可以用一部分水获得;和 无需进行等温线或动力学研究即可获得全面的结果 性能预测(与数学模型不同:例如HSDM)。概述了两种RSSCT测试方法,包括:恒定扩散率(CD),其假设扩散率是恒定的,且与粒径无关;比例扩散率(PD),假设扩散率是线性的,取决于颗粒大小。RSSCT摘要包括: 到目前为止,RSSCT测试结果证明了RSSCT 可作为预测颗粒铁的潜在工具 去除砷(砷酸盐)的氢氧化物(GFH)床寿命; 总体而言,PD方法在较低的, 环境相关、初始浓度和 CD方法可能适用于初始值较高的情况 浓度; 当内部传质不稳定时,PD方法适用 速率限制;和 也适用于其他无机微污染物(例如:。, 磷酸盐)和其他金属氧化物(如粒状铁 氧化物(GFO))。包括数字。
This slide presentation outlines a study where mathematical models were used to scale-down a full-scale adsorber to a rapid small scale column test (RSSCT) and maintain perfect similarity between performance of the adsorbers. Advantages included: breakthrough curves (BTCs) can be obtained in a fraction of the time; BTCs can be obtained with a fraction of the water; and, isotherm or kinetic studies are not required to obtain a full-scale performance prediction (unlike mathematical models: e.g., HSDM). Two RSSCT test approaches are outlined and include: constant diffusivity (CD), which assumes diffusivity is constant and independent of particle size; and, proportional diffusivity (PD), which assumes diffusivity is linear and dependent on particle size. RSSCT Summary includes: RSSCT test results, to date, have demonstrated RSSCT can be a potential tool in predicting granular ferric hydroxide (GFH) bed life for arsenic (arsenate) removal; PD approach, overall, provides best simulation at lower, environmentally relevant, initial concentrations, and CD approach may be applicable under higher initial concentrations; PD approach is applicable when internal mass transfer is rate limiting; and, also applicable to other inorganic micropollutants (e.g., phosphate) and other metal oxides (e.g., granular ferric oxide (GFO)). Includes figures.
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发布单位或类别: 美国-美国给水工程协会
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