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现行 BS PD CEN/TS 15864:2015
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Characterization of waste. Leaching behaviour test for basic characterization. Dynamic monolithic leaching test with continuous leachant renewal under conditions relevant for specified scenario(s) 废物的特性 基本特性的浸出行为测试 在与特定情景相关的条件下进行连续浸出剂更新的动态整体浸出试验
发布日期: 2015-12-31
BS PD CEN/TS 15864:2015适用于测定整体废物的浸出行为 在动态条件下。试验在与评估试验结果相关的实验条件下进行 考虑到所考虑的情况,浸出行为。该测试旨在确定释放量 作为整体废物中无机成分与环境接触时间的函数 水溶液(浸出剂)。一般来说,浸出剂的成分、温度和持续更新率是 选择这样的材料,以便根据所考虑的 处置或恢复场景。当需要在不参考 在特定情况下,浸出剂为软化水、温度和持续更新率 都是固定的。动态整体浸出试验(DMLT)是EN 12920和 因此,其目的不是模拟真实情况。 仅此试验方法的应用并不适用 足以在规定条件下测定整体废物的详细浸出行为 条件在EN 12920的框架内,结合其他化学信息,测试结果 用于确定浸出机制及其相对重要性。内在属性可以 用于预测给定时间范围内成分的释放,以评估浸出 在不同情况或场景下放置的整体废料的行为(包括处置) 以及回收方案)。本试验方法适用于规则形状的整体废物试验部分,其最小 在所有方向上的尺寸均为40 mm,以在一段时间内保持其完整性 与所考虑的场景相关。本试验方法适用于几何尺寸 表面积可以通过简单的几何方程来确定。 本试验方法适用于 低渗透整体材料。注1:如果为了符合规则形状的要求,通过切割或切割来制备试样 取芯,然后暴露新的表面,这可能导致浸出性质的变化。另一方面,如果 试件通过模压制备,表面取决于模具类型和试验条件 存储如果目的是评估材料芯的性能,则样品需要在没有 与空气接触以避免碳化。注2:对于饱和导水率高于10-8 m·s-1的整体废料,水是 可能会渗透到整块岩石中,而不是在其周围流动。在这种情况下,将释放与 几何表面可能导致误解。渗滤测试则更合适(例如CEN/TS 14405)。该程序可能不适用于与浸出剂发生反应的材料,例如导致 气体排放过多或热量释放过多。本文件旨在确定主要无机成分的释放 浪费。它没有考虑有机成分的特殊特性,也没有考虑 有机可降解废物中微生物过程的后果。交叉引用:EN 14346EN 15002EN 16192EN ISO 3696ISO 3696EN ISO 5667-3ISO 5667-3EN 12457-1:2002EN 12920:2006+A1:2008CEN/TS 14405EN 14429EN 14899EN 14997CEN/TS 15862EN 15863CEN/TS 16660AFNOR XP X30-450:2002AFNOR XP X30-467:2002AFNOR XP X30-469:2007ANSI/ANS 16.1:19861999/31/EC2003/33/EC购买本文件时可提供的所有当前修订。
BS PD CEN/TS 15864:2015 is applicable for determining the leaching behaviour of monolithic wastes under dynamic conditions. The test is performed under experimental conditions relevant to assess the leaching behaviour in view of the considered scenario(s). This test is aimed at determining the release as a function of time of inorganic constituents from a monolithic waste, when it is put into contact with an aqueous solution (leachant).In general, the composition, the temperature and the continuous renewal rate of the leachant are chosen such that the leaching behaviour of the waste material can be studied in view of the considered disposal or recovery scenario. When the release needs to be determined without any reference to a specific scenario, the leachant is demineralized water, the temperature and the continuous renewal rate are fixed.This dynamic monolithic leaching test (DMLT) is a parameter specific test as specified in EN 12920 and is therefore not aimed at simulating real situations. The application of this test method alone is not sufficient for the determination of the detailed leaching behaviour of a monolithic waste under specified conditions.In the framework of EN 12920 and in combination with additional chemical information, the test results are used to identify the leaching mechanisms and their relative importance. The intrinsic properties can be used to predict the release of constituents at a given time frame, in order to assess the leaching behaviour of monolithic waste materials, placed in different situations or scenarios (including disposal and recycling scenarios).The test method applies to regularly shaped test portions of monolithic wastes with minimum dimensions of 40 mm in all directions that are assumed to maintain their integrity over a time frame relevant for the considered scenario. The test method applies to test portions for which the geometric surface area can be determined with the help of simple geometric equations. The test method applies to low permeable monolithic materials.NOTE 1 If, in order to comply with the requirements of regular shape, the test portion is prepared by cutting or coring, then new surfaces are exposed which can lead to change(s) in leaching properties. On the other hand if the test portion is prepared by moulding, the surface will be dependent to the type of mould and the conditions of storage. If the intention is to evaluate the behaviour of the material core, the specimen needs to be stored without any contact with air to avoid carbonation.NOTE 2 For monolithic waste materials with a saturated hydraulic conductivity higher than 10-8 m·s-1, water is likely to percolate through the monolith rather than flow around it. In such cases, relating the release to the geometric surface can lead to misinterpretation. A percolation test is then more appropriate (e.g. CEN/TS 14405).This procedure may not be applicable to materials reacting with the leachant, leading for example to excessive gas emission or an excessive heat release.This document has been developed to determine the release of mainly inorganic constituents from wastes. It does not take into account the particular characteristics of organic constituents nor the consequences of microbiological processes in organic degradable wastes.Cross References:EN 14346EN 15002EN 16192EN ISO 3696ISO 3696EN ISO 5667-3ISO 5667-3EN 12457-1:2002EN 12920:2006+A1:2008CEN/TS 14405EN 14429EN 14899EN 14997CEN/TS 15862EN 15863CEN/TS 16660AFNOR XP X30-450:2002AFNOR XP X30-467:2002AFNOR XP X30-469:2007ANSI/ANS 16.1:19861999/31/EC2003/33/ECAll current amendments available at time of purchase are included with the purchase of this document.
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发布单位或类别: 英国-英国标准学会
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