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Standard Test Methods for Determining Oxidation Induction Time of Hydrocarbons by Differential Scanning Calorimetry 用差示扫描量热法测定碳氢化合物氧化诱导时间的标准试验方法
发布日期: 2023-03-15
1.1 这些试验方法描述了通过差示扫描量热法或压力差示扫描量热计测定碳氢化合物的氧化财产,并适用于以分析形式放热氧化的碳氢化合物。 1.2 测试方法A- 差示扫描量热计( 差示扫描量热法 )在环境压力下使用,例如在约100kPa的氧气下使用。 1.3 测试方法B- A压力 差示扫描量热法 ( PDSC公司 )在高压下使用,例如3.5MPa(500psig)的氧气。 1.4 单位- 以国际单位制表示的数值应视为标准。 提供英制单位是为了方便用户,而不是标准单位。 1.5 这些测试方法与ISO 11357-6有关,但在技术内容上有所不同。这些测试方法与CEC L-85–T有关,但包括额外的实验条件。 1.6 本标准并非旨在解决与其使用相关的所有安全问题(如有)。本标准的使用者有责任在使用前制定适当的安全、健康和环境实践,并确定监管限制的适用性。 具体的预防说明见 7.4 和 12.10 . 1.7 本国际标准是根据世界贸易组织技术性贸易壁垒委员会发布的《关于制定国际标准、指南和建议的原则的决定》中确立的国际公认的标准化原则制定的。 ====意义和用途====== 5.1 氧化诱导时间是在测试的等温温度下评估的材料氧化稳定性程度的相对度量。 抗氧化剂的存在、数量或有效性可以通过这种方法来确定。由此获得的OIT值可以从一种烃与另一种烃或与参考材料进行比较,以获得相对氧化稳定性信息。 5.2 典型用途包括食用油和脂肪的氧化稳定性(氧化酸败)、润滑剂、润滑脂和聚烯烃。
1.1 These test methods describe the determination of the oxidative properties of hydrocarbons by differential scanning calorimetry or pressure differential scanning calorimetry and is applicable to hydrocarbons that oxidize exothermically in their analyzed form. 1.2 Test Method A— A differential scanning calorimeter ( DSC ) is used at ambient pressure, for example, about 100 kPa of oxygen. 1.3 Test Method B— A pressure DSC ( PDSC ) is used at high pressure, for example, 3.5 MPa (500 psig) oxygen. 1.4 Units— The values stated in SI units are to be regarded as standard. Imperial units are provided for user convenience and are not the standard. 1.5 These test methods are related to ISO 11357–6 but is different in technical content. These test methods are related to CEC L-85–T but includes additional experimental conditions. 1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in 7.4 and 12.10 . 1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee. ====== Significance And Use ====== 5.1 Oxidative induction time is a relative measure of the degree of oxidative stability of the material evaluated at the isothermal temperature of the test. The presence, quantity or effectiveness of antioxidants may be determined by this method. The OIT values thus obtained may be compared from one hydrocarbon to another or to a reference material to obtain relative oxidative stability information. 5.2 Typical uses include the oxidative stability of edible oils and fats (oxidative rancidity), lubricants, greases, and polyolefins.
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