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Standard Test Method for Polyurethane Raw Materials: Alkalinity in Low-Alkalinity Polyols (Determination of CPR Values of Polyols) 聚氨酯原材料的标准试验方法:低碱度多元醇中的碱度(多元醇CPR值的测定)
发布日期: 2022-03-15
1.1 本试验方法包括测量低碱度(<0.002 meq/g碱度)多元醇中的碱度。这种碱度通常表示为聚醚多元醇的CPR(受控聚合速率)。本试验方法不适用于胺基多元醇。 1.2 以国际单位制表示的数值应视为标准值。 1.3 本标准并非旨在解决与其使用相关的所有安全问题(如有)。本标准的用户有责任在使用前制定适当的安全、健康和环境实践,并确定监管限制的适用性。 注1: 没有已知的ISO等效于本标准。 1.4 本国际标准是根据世界贸易组织技术性贸易壁垒(TBT)委员会发布的《关于制定国际标准、指南和建议的原则的决定》中确立的国际公认标准化原则制定的。 ====意义和用途====== 5.1 该测试方法适用于质量控制、规范测试和研究。众所周知,多元醇和异氰酸酯之间形成聚氨酯聚合物的聚氨酯反应对碱性物质的存在很敏感。这在制备含有异氰酸酯基团的聚氨酯预聚物时尤为重要,已知异氰酸酯基团在存在微量碱性物质的情况下发生反应。由于许多聚醚多元醇通常由强碱催化剂制成,因此重要的是要有一种能够检测少量残留碱性物质的分析方法。本试验方法能够检测碱(如KOH)的ppm水平。 4.
1.1 This test method covers measuring alkalinity in low-alkalinity (<0.002 meq/g basicity) polyols. This alkalinity is often expressed as CPR (controlled polymerization rate) of polyether polyols. This test method is not applicable to amine-based polyols. 1.2 The values stated in SI units are to be regarded as standard. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Note 1: There is no known ISO equivalent to this standard. 1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee. ====== Significance And Use ====== 5.1 This test method is suitable for quality control, as a specification test and for research. The urethane reaction between polyols and isocyanates to form polyurethane polymers is known to be sensitive to the presence of basic substances. This is particularly important in the preparation of polyurethane prepolymers which contain isocyanate groups that are known to react in the presence of trace amounts of basic substances. Since many polyether polyols are often made with strongly basic catalysts, it is important to have an analytical method capable of detecting small quantities of residual basic substances. This test method is capable of detecting ppm levels of base (as KOH). 4
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归口单位: D20.22
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