Nuclear energy — Determination of carbon compounds and fluorides in uranium hexafluoride infrared spectrometry
核能——红外光谱法测定六氟化铀中的碳化合物和氟化物
发布日期:
2003-01-30
ISO 16794:2003规定了用红外光谱法测定六氟化铀(UF6)中作为杂质所含的烃、氯代烃和部分或完全取代的卤代烃或卤代烃的试验方法。
该方法不能用于在UF6(例如CF4)干扰下产生IR射线的化合物。
该检测方法是定量的,适用摩尔分数范围为0,001%或0,0010%,具体取决于杂质类型,最高可达0,100%。
该测试方法也可用于氢氟酸(HF)和以氟化物形式存在的几种元素的测定;硼在BF3中,硅在SiF4中,磷在PF5中,钼在MoF6中,钨在WF6中。
ISO 16794: 2003 specifies a test method for the determination of hydrocarbons, chlorocarbons and partially or completely substituted halocarbons or halohydrocarbons contained as impurities in uranium hexafluoride (UF6) by infrared spectrometry.
This method cannot be used for compounds giving IR rays with interference by UF6 (for example CF4).
The test method is quantitative and applicable in the mole fraction from 0,000 1 % or 0,001 0 %, depending on the type of impurity, up to 0,100 %.
The test method can also be used for the determination of hydrofluoric acid (HF) and several elements existing as fluorides; boron in BF3, silicon in SiF4, phosphorus in PF5, molybdenum in MoF6 and tungsten in WF6.