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UV/TiO2 for Drinking Water Treatment: Concurrent Degradation of 1,4-Dioxane and Removal of Iron and Manganese 饮用水处理用UV/TiO2:同时降解1,4-二氧六环和去除铁和锰
发布日期: 2006-11-01
紫外线与二氧化钛(UV/TiO2)耦合的高级氧化中试 该系统在格林布鲁克水处理厂进行了评估。飞行员的目标 这项研究旨在评估不同操作参数对发动机性能的影响 UV/TiO2系统同时降解1,4-二氧六环并去除铁和氮 锰通过吸附在TiO2表面。据推测,铁和 锰吸附在TiO2表面,会影响1,4-二氧六环的降解。 这项初步研究显示了有希望的结果,表明UV/TiO2高级氧化是可行的 能够同时处理多种污染物。有效的除铁效果显著 在所有测试条件下均能实现,同时有效去除锰和氮 1,4-二氧六环的降解取决于操作条件。较低的流速(8 在碱性条件下(pH值8.6)去除锰需要1/min, 以及在酸性条件下(pH值5.5)或存在 过氧化氢(30毫克/升)。因此,中试UV/TiO2系统能够同时去除铁 锰或1,4-二氧六环,但有效去除锰和降解 1,4-二恶烷是相互竞争的过程。结果表明,紫外线剂量越高(流速越低, 需要使用更多的紫外线灯(或更强大的紫外线灯),以便有效地 清除所有三种污染物。包括26个参考文献、图表。
An ultraviolet light coupled with titanium dioxide (UV/TiO2) advanced oxidation pilot system was evaluated at the Greenbrook Water Treatment Plant. The objective of the pilot study was to evaluate the effect of varying operating parameters on the performance of the UV/TiO2 system for the concurrent degradation of 1,4-dioxane and removal of iron and manganese through adsorption onto the TiO2 surface. It was hypothesized that as iron and manganese adsorb onto the TiO2 surface, the degradation of 1,4-dioxane would be impaired. This pilot study showed promising results that suggest UV/TiO2 advanced oxidation is capable of concurrent treatment of multiple contaminants. Effective iron removal was achieved under all tested conditions, while the effective removal of manganese and degradation of 1,4-dioxane was dependent on operating conditions. A lower flow rate (8 L/min) was required for both the removal of manganese under alkaline conditions (pH 8.6), and the degradation of 1,4-dioxane under acidic conditions (pH 5.5) or in the presence of peroxide (30 mg/L). Thus, the pilot UV/TiO2 system is able to concurrently remove iron with either manganese or 1,4-dioxane, but the effective removal of manganese and degradation of 1,4-dioxane are competing processes. Results suggest that a higher UV dose (lower flow rate, more UV lamps, or more powerful UV lamps) needs to be applied in order to effectively remove all three contaminants. Includes 26 references, figures.
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发布单位或类别: 美国-美国给水工程协会
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