Pilot Testing, Full-Scale Design and Operational Results for Wellhead Treatment for Color, Arsenic and Hydrogen Sulfide Removal for the City of Hanford, California
加利福尼亚州汉福德市去除颜色、砷和硫化氢井口处理的中试、全尺寸设计和运行结果
In 1997, the City selected Boyle Engineering Corporation (Boyle) to investigate treatment
methods to reduce the color and the hydrogen sulfide in the water from Well 37. In addition,
arsenic reduction treatment was desired if possible. Based on previous pilot testing of Hanford's
water for arsenic reduction using oxidation, precipitation, and a proprietary filtration process, a
pilot program utilizing two manufacturers (Filtronics, Inc. and Pureflow Filtration Division) was
recommended.
The proprietary filtration process (PFP) utilizes a proprietary multimedia within an enclosed
pressure vessel. In general, raw water is pretreated in a reaction vessel using chlorine, sodium
bisulfite, and possibly ferric chloride prior to filtration. In these treatment systems iron,
manganese, hydrogen sulfide, and arsenic are oxidized. The hydrogen sulfide is oxidized to
sulfate. The iron and manganese are precipitated as hydroxides, adsorbing the arsenic. The
addition of ferric chloride assists in further reducing the arsenic. The arsenic is removed in the
media-filled pressure vessel as an iron/arsenic or manganese/arsenic precipitate. The filter media
requires no regeneration but must be backwashed periodically like a conventional sand filter.
The backwash water is directed to a settling tank where the backwash water can be decanted and
recycled to the head of the plant. The resulting sludge (and sometimes the entire backwash
water) can be disposed of to a sewer or to on-site sludge-drying beds.
Multiple pilot tests were performed at Well 37 by both Filtronics and Pureflow during 1997 and
1998. The purpose of these tests was to demonstrate the treatment capabilities to meet two-phased
treatment objectives. The two-phased treatment objective unique to Hanford's
operational goals, water quality standard compliance, and budget is discussed in this paper. Includes tables, figures.