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Standard Practices for Dissolving Glass Containing Radioactive and Mixed Waste for Chemical and Radiochemical Analysis 化学和放射化学分析用溶解含有放射性和混合废物的玻璃的标准实施规程
发布日期: 2019-02-01
1.1 这些实践包括适用于溶解可能含有核废料的玻璃样品的技术。这些技术结合使用或单独使用将产生可通过电感耦合等离子体原子发射光谱法(ICP-AES)、电感耦合等离子体质谱法(ICP-MS)、原子吸收光谱法(AAS)、放射化学方法和湿化学技术对主要组分、次要组分和放射性核素进行分析的溶液。 1.2 其中一种融合实践和微波实践可以在修改后用于热电池和屏蔽罩,以满足当地操作要求。 1.3 这些实践的用户必须遵守针对其特定实验室的辐射防护指南。 1.4 与安全相关的其他信息包含在文本中。 1.5 这些实践中描述的溶解技术可用于玻璃化核废料工厂的原料和产品的质量控制。 1.6 介绍这些实践是为了向用户提供测试方法的替代方法 C169 用于在屏蔽设施中溶解含玻璃的废物。试验方法 C169 不适用于此类设施和放射性材料。 1.7 试验方法中的ICP-AES方法 C1109 和 C1111 可用于分析溶解样品,必要时进行额外的样品制备,并考虑基质效应。有关其他分析方法的更多信息,请参见测试方法 C169 . 1.8 在建立实验室性能标准并验证符合标准后,本规程中的溶液可能适用于使用ICP-MS进行分析。例如,测试方法 C1287 或 C1637 根据需要和适当的基质效应考虑,可与额外的样品制备一起使用。 1.9 以国际单位制表示的数值应视为标准值。括号中的单位仅供参考。 1.10 本标准并非旨在解决与其使用相关的所有安全问题(如有)。本标准的用户有责任在使用前制定适当的安全、健康和环境实践,并确定监管限制的适用性。 第节给出了具体的预防说明 10 , 20 和 30 . 1.11 本国际标准是根据世界贸易组织技术性贸易壁垒(TBT)委员会发布的《关于制定国际标准、指南和建议的原则的决定》中确立的国际公认标准化原则制定的。
1.1 These practices cover techniques suitable for dissolving glass samples that may contain nuclear wastes. These techniques used together or independently will produce solutions that can be analyzed by inductively coupled plasma atomic emission spectroscopy (ICP-AES), inductively coupled plasma mass spectrometry (ICP-MS), atomic absorption spectrometry (AAS), radiochemical methods and wet chemical techniques for major components, minor components and radionuclides. 1.2 One of the fusion practices and the microwave practice can be used in hot cells and shielded hoods after modification to meet local operational requirements. 1.3 The user of these practices must follow radiation protection guidelines in place for their specific laboratories. 1.4 Additional information relating to safety is included in the text. 1.5 The dissolution techniques described in these practices can be used for quality control of the feed materials and the product of plants vitrifying nuclear waste materials in glass. 1.6 These practices are introduced to provide the user with an alternative means to Test Methods C169 for dissolution of waste containing glass in shielded facilities. Test Methods C169 is not practical for use in such facilities and with radioactive materials. 1.7 The ICP-AES methods in Test Methods C1109 and C1111 can be used to analyze the dissolved sample with additional sample preparation as necessary and with matrix effect considerations. Additional information as to other analytical methods can be found in Test Method C169 . 1.8 Solutions from this practice may be suitable for analysis using ICP-MS after establishing laboratory performance criteria and verification that the criteria can be met. For example, Test Methods C1287 or C1637 may be used with additional sample preparation as necessary and appropriate matrix effect considerations. 1.9 The values stated in SI units are to be regarded as standard. Units in parentheses are for information only. 1.10 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in Sections 10 , 20 , and 30 . 1.11 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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归口单位: C26.05
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