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现行 BS EN 14405:2017
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Characterization of waste - Leaching behaviour test - Up-flow percolation test (under specified conditions) 废物的特性 浸出行为试验 上流式渗滤试验(在规定条件下)
发布日期: 2017-03-31
BS EN 14405:2017适用于测定无机物和非挥发性物质的浸出行为 颗粒废物中的有机物质(未经或有尺寸缩小(见7.2))。废物体是 在规定的渗滤条件下,以水作为液固比的函数进行渗滤 条件废物在水力动态条件下浸出。这种方法是一次性的 柱浸试验和试验结果确定了不同释放模式之间的区别,例如 实例:接近局部时,在与基质相互作用的影响下冲洗和释放 废物和浸出剂之间的平衡。本试验方法产生洗脱液,随后可进行 根据现有标准方法,以物理、化学和生态毒理学方法为特征。注1:上述指定渗流条件是任意的,不一定模拟特定的渗流条件 脚本注2:饱和导水率在10-7 m/s和10-8 m/s之间的废料可以 进行该试验,但可能难以维持施加的流速。如果垃圾显示出饱和水力 电导率低于10-8 m/s时,最好不要进行试验(参见C.5中“水力”的定义 电导率”)。注3:本程序通常不适用于生物降解材料和与之反应的材料 例如,浸出剂会导致气体过度排放或热量过度释放。注4:本程序适用于显示柱内固化的材料,如果最终液压试验 电导率在规定范围内(见注2)。注5:对于无机物和非挥发性有机物,并非总是能够同时优化试验条件 不同类别的非挥发性有机物质的物质和最佳试验条件也可能有所不同。非挥发性有机物的测试要求通常比无机物更严格 成分。适用于测量非挥发性有机物质释放的试验条件通常为: 也适用于无机物质。注6:对于生态毒理学测试,代表无机物和非挥发性有机物释放的洗脱液 物质是必需的。在本标准中,生态毒理学测试也包括基因毒理学测试。注7:非挥发性有机物的验证数据目前不可用,但将在修订时添加 如果有的话。交叉引用:EN 14346EN 14899EN 15002EN 16192EN ISO 3696ISO 3696EN ISO 5667-3ISO 5667-3EN 12457- 1:2002EN 12457-2:2002EN 12457-3:2002EN 12457-4:2002EN 12920:2006+A1:2008EN 14429:2015EN 14997:2015CEN/TS 16637-3:2016CEN ISO/TS 21268-3:2009ISO/TS 21268-3:2007ISO 5725-2:1994ISO 11464:2006NEN 7343:1995NT ENVIR 002:19951999/31/EC2003/33/ECUS EPA SWA-846购买本文件时可用的所有现行修订均包含在购买本文件中。
BS EN 14405:2017 is applicable for determining the leaching behaviour of inorganic and non-volatile organic substances from granular waste (without or with size reduction (see 7.2)). The waste body is subjected to percolation with water as a function of liquid to solid ratio under specified percolation conditions. The waste is leached under hydraulically dynamic conditions. The method is a once-through column leaching test and the test results establish the distinction between different release patterns, for instance wash-out and release under the influence of interaction with the matrix, when approaching local equilibrium between waste and leachant. This test method produces eluates, which can subsequently be characterized by physical, chemical and ecotoxicological methods according to existing standard methods.NOTE 1 The mentioned specified percolation conditions are arbitrary and are not necessarily simulating a specific scenario.NOTE 2 Waste materials that show a saturated hydraulic conductivity between 10-7 m/s and 10-8 m/s can be subjected to this test, but it can be difficult to maintain the imposed flow rate. If a waste shows a saturated hydraulic conductivity below 10-8 m/s, the test will preferably not be carried out (See C.5 for a definition of 'hydraulic conductivity').NOTE 3 This procedure is generally not applicable to biologically degrading materials and materials reacting with the leachant, leading, for example, to excessive gas emission or excessive heat release.NOTE 4 This procedure is applicable to materials showing solidification in the column, if the final hydraulic conductivity is within the specified range (see NOTE 2).NOTE 5 It is not always possible to optimise test conditions simultaneously for inorganic and non-volatile organic substances and optimum test conditions may also vary between different groups of non-volatile organic substances.Test requirements for non-volatile organic substances are generally more stringent than those for inorganic constituents. The test conditions suitable for measuring the release of non-volatile organic substances will generally also be applicable to inorganic substances.NOTE 6 For ecotoxicological testing, eluates representing the release of both inorganic and non-volatile organic substances are needed. In this standard ecotoxicological testing is meant to include also genotoxicological testing.NOTE 7 Validation data for non-volatile organic substances are not currently available, but will be added on revision when available.Cross References:EN 14346EN 14899EN 15002EN 16192EN ISO 3696ISO 3696EN ISO 5667-3ISO 5667-3EN 12457-1:2002EN 12457-2:2002EN 12457-3:2002EN 12457-4:2002EN 12920:2006+A1:2008EN 14429:2015EN 14997:2015CEN/TS 16637-3:2016CEN ISO/TS 21268-3:2009ISO/TS 21268-3:2007ISO 5725-2:1994ISO 11464:2006NEN 7343:1995NT ENVIR 002:19951999/31/EC2003/33/ECUS EPA SWA-846All current amendments available at time of purchase are included with the purchase of this document.
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发布单位或类别: 英国-英国标准学会
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