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Integrity Evaluation of New Generation Reverse Osmosis Membranes During Municipal Wastewater Reclamation 新一代反渗透膜在城市污水回用中的完整性评价
发布日期: 2006-11-01
MWH和圣地亚哥市最近在北城完成了一项试点测试项目 位于加利福尼亚州圣地亚哥的水回收厂(NCWRP)。测试项目的目的是: 评估反渗透膜完整性和完整性监测的各个方面。在本研究中 使用以下方法评估了用于水回用应用的新一代反渗透膜的完整性: 传统方法,如真空衰变测试、容器探测、在线电导率和硫酸盐测试 用可溶性染料和MS2噬菌体进行监测和挑战性试验。此外,提出了一种新的反渗透方法 对使用TRASAR®化学品的Nalco公司开发的完整性监测进行了评估。这个 反渗透膜清除特定内分泌干扰物(EDC)和 药品和个人护理产品(PPCP)通过对饲料和渗透液取样进行评估 并对每个系统进行评估,以确定城市生活中常见的29种化合物的目标清单 废水。最后,测试的完整性方法在检测完整性违规方面的敏感性以及 完整性对EDC/PPCP通道的影响是通过故意破坏其中一个RO来确定的 膜系统和重复测试。这项研究的结果表明,MS2噬菌体被 新一代反渗透膜在2-4对数之间变化(即99%-99.99%)。此外,调查结果 在与MS2去除相关的每个膜上测试的各种监测方法;然而 这些方法的灵敏度各不相同。例如,电导率监测提供了~2个测井点的清除, 硫酸盐监测~3原木去除和可溶性染料测试~4原木去除。挑战测试 TRASAR® 表明所提出的方法有可能提供高度敏感的(>6 log) 完整性监控级别。EDC/PPCP分析显示,所有新一代反渗透膜都完好无损 经过测试的系统将进料废水中的部分化合物去除至接近或低于MDL的水平 (纳克/升)。结果还表明,某些EDC/PPCP化合物具有不同的去除机制和性能 因此,与完整性妥协相关的通过量的增加可能因化合物和 违约类型。包括11个参考文献、表格、图表。
MWH and the City of San Diego have recently completed a pilot testing program at the North City Water Reclamation Plant (NCWRP) located in San Diego, CA. The purpose of the testing program was to evaluate various aspects of RO membrane integrity and integrity monitoring. During this study the integrity of new generation RO membranes offered for water reuse applications was assessed using traditional methods such as vacuum decay testing, vessel probing, on-line conductivity and sulfate monitoring and challenge testing with soluble dye and MS2 phage. In addition, a new method of RO integrity monitoring developed by Nalco Company which uses TRASAR® chemical was evaluated. The ability of the RO membranes to remove select endocrine disrupting compounds (EDCs) and pharmaceuticals and personal care products (PPCPs) was assessed by sampling feed and permeate of each system and evaluating them for a target list of 29 compounds commonly found in municipal wastewater. Lastly, the sensitivity of the tested integrity methods at detecting integrity breaches and the impact of integrity on EDC/PPCP passage were determined by purposely breaching one of the RO membrane systems and repeating testing. Results of this study showed the removal of MS2 phage by new generation RO membranes varied between 2-4 log (i.e. 99%-99.99%). In addition, results of the various monitoring methods tested on each membrane correlated to MS2 removal; however, the sensitivity of the methods varied. For instance, conductivity monitoring provided ~2 log removal, sulfate monitoring ~3 log removal and soluble dye testing ~ 4 log removal. Challenge testing with TRASAR® showed that the proposed method has the potential to provide a highly sensitive (>6 log) level of integrity monitoring. EDC/PPCP analysis showed all intact new generation RO membrane systems tested removed select compounds present in the feed wastewater to levels near or below MDL (ng/L). Results also suggest that certain EDC/PPCP compounds have different removal mechanisms and therefore, the increase in passage related to compromises in integrity may vary by compound and the type of breach. Includes 11 references, tables, figures.
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发布单位或类别: 美国-美国给水工程协会
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