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Influence of Membrane Surface Properties and Feed Water Qualities on RO/NF Mass Transfer 膜表面性质和进水水质对RO/NF传质的影响
发布日期: 2004-06-17
研究了膜的表面特性和天然有机物(NOM)对膜性能的影响 意义重大但未被充分理解。本研究调查了膜表面特性和 NOM对不同预处理和预处理条件下膜性能的影响 膜。表面电荷、疏水性和粗糙度各不相同 在研究中使用的四种膜中,这一点尤为明显。对膜进行了测试 在两个不同的预处理过程之后,一个增强的Zenon 反渗透(RO)前的超滤工艺(ZN)和紧凑型CSF工艺(超级脉冲发生器(SP)) 膜处理共有八个集成膜系统。全膜 系统暴露于类似的温度、回收率和通量以及化学物质 剂量锌预处理和SP处理后的给水水质相同 除NOM浓度外的预处理。膜表面特性 SUVA测量用于描述低压RO中的传质 集成膜系统。计算了溶质和水的传质系数 系统地研究了膜表面性质和NOM的依赖性 质量负荷。 无机MTC由高斯分布曲线精确描述。 随着膜厚度的增加,水分生产率、NOM截留率和无机物截留率增加 表面电荷和NOM负荷增加。无机MTC也与 表面疏水性和表面粗糙度。同一介质的渗透率变化 膜与NOM负荷、疏水性和粗糙度有关。有机污染 通过水的测量,有机质和无机质的转移对于具有 更高的亲水性和粗糙度。包括19个参考文献、表格和图表。
The influence of surface characteristics and natural organic matter (NOM) on membrane performance is significant but not well understood. This study investigated the impact of membrane surface characteristics and NOM on membrane performance for varying pretreatment and membranes. Surface charge, hydrophobicity and roughness varied significantly among the four membranes used in the study. The membranes were tested in parallel following two different pretreatment processes, an enhanced Zenon ultrafiltration process (ZN) and a compact CSF process (Superpulsator (SP)) prior to reverse osmosis (RO) membrane treatment for a total of eight integrated membrane systems. All membrane systems were exposed to the similar temperature, recovery and flux as well as chemical dosage. The feed water qualities were identical following ZN pretreatment and SP pretreatment except for NOM concentration. Membrane surface characteristics, NOM and SUVA measurements were used to describe mass transfer in a low pressure RO integrated membrane system. Solute and water mass transfer coefficients were systematically investigated for dependence on membrane surface properties and NOM mass loading. Inorganic MTCs were accurately described by a Gaussian distribution curve. Water productivity, NOM rejection and inorganic rejection increased as membrane surface charge and NOM loading increased. Inorganic MTCs were also correlated to surface hydrophobicity and surface roughness. The permeability change of identical membranes was related to NOM loading, hydrophobicity and roughness. Organic fouling as measured by water, organic and inorganic mass transfer was less for membranes with higher hydrophilicity and roughness. Includes 19 references, tables, figures.
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发布单位或类别: 美国-美国给水工程协会
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