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现行 ASTM D3635-13(2021)
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Standard Test Method for Dissolved Copper In Electrical Insulating Oil By Atomic Absorption Spectrophotometry 原子吸收分光光度法测定电绝缘油中溶解铜的标准试验方法
发布日期: 2021-12-01
1.1 本试验方法包括用原子吸收分光光度法测定新的或使用过的石油绝缘油中的铜。 1.2 可检测性的最低限度主要取决于雾化方法,但也取决于能源、燃料和氧化剂以及输出信号的电膨胀程度。最低可检测浓度通常被认为等于背景最大变化的两倍。对于火焰雾化,可检测性的下限通常为0.1 ppm或0.1 mg/kg。对于非火焰雾化,可检测性下限小于0。 01 ppm。 1.3 以国际单位制表示的数值应视为标准值。本标准不包括其他计量单位。 1.4 本标准并非旨在解决与其使用相关的所有安全问题(如有)。本标准的用户有责任在使用前制定适当的安全、健康和环境实践,并确定监管限制的适用性。 1.5 本国际标准是根据世界贸易组织技术性贸易壁垒(TBT)委员会发布的《关于制定国际标准、指南和建议的原则的决定》中确立的国际公认标准化原则制定的。 ====意义和用途====== 4.1 电绝缘油可能含有少量溶解金属,这些金属直接来自基础油或在精炼或使用过程中与金属接触。当铜存在时,它作为催化剂促进油的氧化。该试验方法有助于研究新油和评估使用老化油的状况。应考虑范围中概述的检测极限。
1.1 This test method covers the determination of copper in new or used electrical insulating oil of petroleum origin by atomic absorption spectrophotometry. 1.2 The lowest limit of detectability is primarily dependent upon the method of atomization, but also upon the energy source, the fuel and oxidant, and the degree of electrical expansion of the output signal. The lowest detectable concentration is usually considered to be equal to twice the maximum variation of the background. For flame atomization, the lower limit of detectability is generally in the order of 0.1 ppm or 0.1 mg/kg. For non-flame atomization, the lower limit of detectability is less than 0.01 ppm. 1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee. ====== Significance And Use ====== 4.1 Electrical insulating oil may contain small amounts of dissolved metals derived either directly from the base oil or from contact with metals during refining or service. When copper is present, it acts as a catalyst in promoting oxidation of the oil. This test method is useful for research for new oils and to assess the condition of service-aged oils. Consideration should be given to the limits of detection outlined in the scope.
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归口单位: D27.03
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