Water quality. Determination of organochlorine pesticides (OCP) in whole water samples. Method using solid phase extraction (SPE) with SPE-disks combined with gas chromatography mass spectrometry (GC-MS)
水质 全水样中有机氯农药(OCP)的测定 固相萃取(SPE)结合气相色谱-质谱(GC-MS)的方法
发布日期:
2015-09-30
BS EN 16693:2015规定了选定有机氯农药的测定方法
(OCP)(见表1),在水样中。该方法采用固相萃取法,固相萃取盘紧随其后
通过气相色谱-质谱(GC-MS)。适用于表面有机氯农药的分析
含悬浮颗粒物(SPM)高达500 mg/l(全水样)的水,饮用
水和地下水。工作范围的下限取决于矩阵,具体取决于
待分析化合物,并取决于质谱检测装置的灵敏度。对于
表1所列化合物的测定限(LOQ)至少为相应AAEQ的30%
符合欧洲质量标准要求的值(0000 15微克/升至0.1微克/升)
内陆地表水和其他地表水的指令(指令2008/105/EC)。该方法可用于分析表1中未列出的其他OCP或其他类型的水。
然而,重要的是在使用前验证其适用性。交叉引用:EN ISO 3696ISO 3696EN ISO 5667-3ISO 5667-3EN ISO 5667-1ISO 5667-1EN ISO 22892ISO 22892ISO 8466-1ISO 5725-2ISO/TS 285812000/60/EC2008/105/EC2009/90/EC2013/39/EUSANCO/12571/2013购买本文件时提供的所有现行修订版均包含在购买本文件中。
BS EN 16693:2015 specifies a method for the determination of selected organochlorine pesticides
(OCP) (see Table 1), in water samples. The method uses solid-phase extraction with SPE-disks followed
by gas chromatography-mass spectrometry (GC-MS). It is applicable to the analysis of OCPs in surface
water containing suspended particulate matter (SPM) up to 500 mg/l (whole water samples), drinking
water and groundwater. The lower limit of the working range depends on the matrix, on the specific
compound to be analyzed and on the sensitivity of the mass spectrometric detection unit. For
compounds listed in Table 1 the limit of determination (LOQ) is at least 30 % of the corresponding AAEQS
value (0,000 15 µg/l to 0,1 µg/l) according to the requirements of the European Quality Standards
Directive (Directive 2008/105/EC) for both inland surface waters and other surface waters.This method may be used for the analysis of other OCPs not listed in Table 1 or other types of water.
However, it is important to verify its applicability before use.Cross References:EN ISO 3696ISO 3696EN ISO 5667-3ISO 5667-3EN ISO 5667-1ISO 5667-1EN ISO 22892ISO 22892ISO 8466-1ISO 5725-2ISO/TS 285812000/60/EC2008/105/EC2009/90/EC2013/39/EUSANCO/12571/2013All current amendments available at time of purchase are included with the purchase of this document.