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Standard Test Method for Determination of Trace Quantities of Iron by Visible Spectrophotometry 用可见分光光度法测定痕量铁的标准试验方法
发布日期: 2022-05-01
1.1 本试验方法包括使用[3-(2-吡啶基)-5,6-双(4-苯磺酸)-1,2,4-三嗪、单钠盐、一水合物](PDT)测定0.01至0.2μg/g范围内的芳烃及其衍生物和相关化学品中的铁 2. 试剂溶液。可通过使用5或10 cm试管或适当稀释样品溶液来扩大范围。 1.2 铁的检测限(LOD)为0.01µg/kg,定量限(LOQ)为0.04µg/kg。 注1: LOD和LOQ是使用ILS的数据计算的。 1.3 本试验方法适用于铁测定的最后步骤,不包括样品制备程序。 1.4 以国际单位制表示的数值应视为标准值。本标准不包括其他计量单位。 1.5 有关毒性、急救程序和安全预防措施的详细信息,请查看当前的安全数据表(SDS)。 1.6 本标准并非旨在解决与其使用相关的所有安全问题(如有)。本标准的用户有责任在使用前制定适当的安全、健康和环境实践,并确定监管限制的适用性。 有关具体的警告声明,请参阅第节 8. . 1.7 本国际标准是根据世界贸易组织技术性贸易壁垒(TBT)委员会发布的《关于制定国际标准、指南和建议的原则的决定》中确立的国际公认标准化原则制定的。 ====意义和用途====== 4.1 本试验方法适用于测定各种产品中的微量铁浓度,前提是适当的样品制备使铁和样品基质可溶于水或其他合适的溶剂。必须使用本试验方法调查每个样品基质的适用性。 4.2 本试验方法假设显色量与试验溶液中的铁量成比例。校准曲线在指定范围内呈线性。
1.1 This test method covers the determination of iron in aromatic hydrocarbons, their derivatives, and related chemicals in the range from 0.01 to 0.2 μg/g using [3-(2-pyridyl)-5,6-bis(4-phenylsulfonic acid)-1,2,4-triazine, monosodium salt, monohydrate] (PDTS) 2 reagent solution. The range may be extended through the use of a 5- or 10-cm cell or by suitable dilution of the sample solution. 1.2 The limit of detection (LOD) is 0.01 µg/kg for iron and the limit of quantitation (LOQ) is 0.04 µg/kg. Note 1: The LOD and LOQ were calculated using data from the ILS. 1.3 This test method is intended to be general for the final steps in the determination of iron and does not include procedures for sample preparation. 1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.5 Review the current Safety Data Sheets (SDS) for detailed information concerning toxicity, first-aid procedures, and safety precautions. 1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see Section 8 . 1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee. ====== Significance And Use ====== 4.1 This test method is suitable for determining trace concentrations of iron in a wide variety of products, provided that appropriate sample preparation has rendered the iron and sample matrix soluble in water or other suitable solvent. Each sample matrix must be investigated for suitability using this test method. 4.2 This test method assumes that the amount of color developed is proportional to the amount of iron in the test solution. The calibration curve is linear over the specified range.
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归口单位: D16.04
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