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Petroleum and related products — Determination of low concentration of sulfur in automotive fuels — Energy-dispersive X-ray fluorescence spectrometric method 石油及相关产品汽车燃料中低浓度硫的测定能量色散X射线荧光光谱法
发布日期: 2024-08-15
本文件规定了用于测定汽车燃料中硫含量的能量色散X射线荧光(EDXRF)测试方法。本文件适用于: -含有至多3.7质量%氧的汽油(包括与至多10体积%乙醇共混的汽油),硫含量在6.9 mg/kg至56.7 mg/kg的范围内, -柴油燃料,包括按体积计含有至多约30%脂肪酸甲酯(FAME)的那些、链烷烃柴油燃料和纯FAME,其硫含量在5.0 mg/kg至60.2 mg/kg的范围内。 其他产品中的硫含量可按本文件规定的试验方法测定;然而,本文件未建立除车用燃料以外的产品和超出规定范围的结果的精密度数据。由于光谱重叠的原因,本文件不适用于含铅车用汽油、铅含量大于8mg/kg的汽油或含铅、硅、磷、钙、钾或卤化物的产品和原料,其浓度大于测得的硫浓度的十分之一,或大于10mg/kg,以较大者为准。

This document specifies an energy dispersive X-ray fluorescence (EDXRF) test method for the determination of sulfur content in automotive fuels. This document is applicable to:

    gasoline containing up to 3,7 % oxygen by mass (including those blended with ethanol up to 10 % by volume) having sulfur contents in the range of 6,9 mg/kg to 56,7 mg/kg,

    diesel fuels including those containing up to about 30 % fatty acid methyl ester (FAME) by volume, paraffinic diesel fuel, and neat FAME, having sulfur contents in the range of 5,0 mg/kg to 60,2 mg/kg.

The sulfur content in other products can be determined according to the test method specified in this document; however, no precision data for products other than automotive fuels and for results outside the specified range have been established for this document.

For reasons of spectral overlap, this document is not applicable to leaded automotive gasoline, gasoline having a content of greater than 8 mg/kg lead or to product and feedstock containing lead, silicon, phosphorus, calcium, potassium or halides at concentrations greater than one tenth of the concentration of sulfur measured, or more than 10 mg/kg, whichever is the greater.

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归口单位: ISO/TC 28
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