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Water Quality Factors Affecting Hydroxyl Radicals and Bromate Formation During Ozonation 影响臭氧氧化过程中羟基自由基和溴酸盐生成的水质因素
发布日期: 2003-11-02
臭氧氧化过程中羟基自由基(HO)和溴酸盐的形成受到强烈影响 受水质和处理变量的影响。HO的量化CT值确定,表示为HO的比率暴露(或 臭氧暴露(或浓度)。进行了两个阶段的RCT 在整个臭氧氧化过程中,RCT的值在任何特定时间都保持不变 处理一组水质。 各范围之间存在线性关系 水质参数和HO溴酸盐形成的浓度或速率。溴酸盐 可以通过添加酸或氨来抑制中间体OBr-来控制生成。 将水的pH值从环境(8.2)降低到7.5和6.5的酸添加量会减少溴酸盐 形成率分别为30%和80%。相比之下,添加氨水可以降低成本 在pH值为7.5和8.5时,溴酸盐的生成率分别高达60%和85%。随着水的pH值降低,氨水减少溴酸盐生成的效率降低。 包括7个参考文献、表格、图表。
Formation of hydroxyl radicals (HO.) and bromate during ozonation is strongly influenced by water quality and treatment variables. Quantification of HO. was determined by introducing the RCT value, expressed as a ratio of HO. exposure (or concentration) to ozone exposure (or concentration). Two phases of RCT were performed and the values of RCT remain unchanged at any specific time throughout the ozonation process with a set of water quality. Linear relationships were observed between extents of water quality parameters and HO. concentration or rate of bromate formation. Bromate formation can be controlled by adding acid or ammonia to depress intermediate OBr-. Acid addition to lower water pH from ambient (8.2) to 7.5 and 6.5 reduced bromate formation by 30% and 80%, respectively. In comparison, adding ammonia reduced bromate formation up to 60% and 85% at pH 7.5 and 8.5, respectively. Ammonia's efficiency to mitigate bromate formation was lessened with lowered water pH. Includes 7 references, tables, figures.
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发布单位或类别: 美国-美国给水工程协会
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