1.1
This test method covers a procedure for constant immersion exfoliation corrosion (EXCO) testing of high-strength 2XXX (see
Note 2
) and 7XXX series aluminum alloys.
Note 1:
This test method was originally developed for research and development purposes; however, it is referenced, in specific material specifications, as applicable for evaluating production material (refer to Section
14
on Precision and Bias).
Note 2:
Some Al-Cu-Li alloys are registered in the 2xxx family. This test method has been reported as non representative of performance in outdoor atmospheres for various Al-Cu-Li alloys in both as-quenched and artificially aged tempers.
2
1.2
This test method applies to all wrought products such as sheet, plate, extrusions, and forgings produced from conventional ingot metallurgy process.
1.3
This test method can be used with any form of specimen or part that can be immersed in the test solution.
1.4
This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.5
This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
====== Significance And Use ======
5.1
This test method was originally developed for research and development purposes; however, it is referenced, in specific material specifications, as applicable for evaluating production material (refer to Section
14
on Precision and Bias).
5.2
Use of this test method provides a useful prediction of the exfoliation corrosion behavior of these alloys in various types of outdoor service, especially in marine and industrial environments.
5
The test solution is very corrosive and represents the more severe types of environmental service, excluding, of course, unusual chemicals not likely to be encountered in natural environments.
5.3
The exfoliation ratings were arbitrarily chosen to illustrate a wide range in resistance to exfoliation in this test. However, it remains to be determined whether correlations can be established between EXCO test ratings and realistic service conditions for a given alloy. For example, it has been reported
6
that samples of Al-Zn-Mg-Cu alloys rated EA or P in a 48 h EXCO test did not develop more than a slight amount of incipient exfoliation (EA) during six- to nine-year exposures to seacoast atmospheres, whereas, ED rated materials in most cases developed severe exfoliation within a year in the seacoast atmosphere.