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现行 BS ISO 17183:2016
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Soil quality. Screening soils for isopropanol-extractable organic compounds by determining emulsification index by light attenuation 土壤质量 通过光衰减测定乳化指数筛选土壤中异丙醇可萃取有机化合物
发布日期: 2016-04-30
BS ISO 17183:2016规定了筛选高污染土壤进行检测的程序 可用异丙醇萃取的有机化合物,包括多种燃料、油和油脂。 这种方法对寻找热点很有用。它适用于实验室和现场筛选 在野外。工作范围约为0.01至0.3(以吸光度单位表示),对应于 土壤中约500 mg/kg至10000 mg/kg的异丙醇可提取有机化合物。 这种方法对寻找热点很有用。它适用于实验室和现场筛选 在野外。工作范围约为0.01至0.3(以吸光度单位表示),对应于 土壤中约500 mg/kg至10000 mg/kg的异丙醇可提取有机化合物。 该方法中的光散射/吸收方法的光衰减旨在快速 使用校准筛选土壤样品,并使用土壤上可能存在的最合适物质 给出现场指示浓度水平。这种筛选技术适用于广泛的有机化合物,主要是 碳氢化合物。有机化合物是一种定义非常广泛的化合物混合物,它显示出 自身特定乳化指数(见附录A)和混合物样品中的总乳化指数, 主要由它们在水中的不溶性来定义。化合物的不溶性越强(例如非极性 化合物),反应越高。碳氢化合物通常反应性较低,极性较小。 乳化指数的测定使用非乳化指数- 检测有机化合物的极性性质 包括范围广泛的碳氢化合物,从大约C8到大约C36。注:该方法也适用于植物油等生物物质。本方法不适用于特定有机化合物或化合物组的测定 这可能是更大的有机化合物混合物的一部分。与其他筛查技术一样,它是 建议确认一定百分比的阳性和阴性检测结果,尤其是在 接近或高于监管行动限制,或存在背景或干扰有机物时 怀疑存在表面活性物质等化合物。该方法不涉及任何挥发性有机化合物混合物的蒸发(即:。, (汽油)在取样、制备和检测过程中。 虽然可以使用筛选方法 对于挥发性碳氢化合物的定量检测,不打算将该方法用于 挥发性石油烃的定量测定,除非在取样过程中蒸发 处理问题;应对响应系数进行适当修正,或对方法性能进行评估 在真实样品上演示。如果存在乳化剂或表面活性物质(如洗涤剂),则会产生明显的负偏倚 或者可以得到假阴性结果。如果有任何证据表明 土壤,这种方法不能应用。交叉引用:ISO 11074ISO 10381-5ISO 11464ISO 12404ISO 17381ISO/IEC指南98购买本文件时提供的所有当前修订版均包含在购买本文件中。
BS ISO 17183:2016 specifies the procedure to screen highly contaminated soils to detect organic compounds extractable with isopropanol, including a wide range of fuels, oils, and greases. The method is useful for finding hot spots. It is applicable both in laboratories and for site screening in the field. The working range is approximately 0,01 to 0,3 in absorbance units, corresponding to approximately 500 mg/kg to 10 000 mg/kg of isopropanol-extractable organic compounds in soil. The method is useful for finding hot spots. It is applicable both in laboratories and for site screening in the field. The working range is approximately 0,01 to 0,3 in absorbance units, corresponding to approximately 500 mg/kg to 10 000 mg/kg of isopropanol-extractable organic compounds in soil.The light attenuation due to light scattering/absorption approach in this method is designed to quickly screen soil samples using calibration with the most appropriate substance(s) likely to be present on a given site to indicate the concentration levels.This screening technique is applicable for a broad spectrum of organic compounds, mainly hydrocarbons. Organic compounds are a very broadly defined mixture of compounds, which show their own specific emulsification indices (see Annex A) and a gross emulsification index in a mixture sample, defined primarily by their insolubility in water. The more insoluble the compounds (e.g. non-polar compounds), the higher the response. Hydrocarbons are generally less-reactive and have little polarity. Determination of emulsification indexes uses their non-polar nature to detect organic compounds including a wide range of hydrocarbons from about C8 to about C36.NOTE This method can also be applied to biological substances such as vegetable oils.This method is not applicable for determination of specific organic compounds or groups of compounds that may be part of a larger organic compound mixture. As with other screening techniques, it is advisable to confirm a certain percentage of both positive and negative test results, especially when near or above a regulatory action limit or when the presence of background or when interfering organic compounds such as surface active substances are suspected to be present.This method does not address the evaporation of any volatile organic compound mixtures (i.e., gasoline) during sampling, preparation and detection. Although the screening method can be used for the quantitative detection of volatile hydrocarbons, it is not intended that the method be used for the quantitative determination of volatile petroleum hydrocarbons unless evaporation during sample handling is addressed; the response factor be appropriately corrected, or the method performance be demonstrated on real samples.If emulsifiers or surface active substances (e.g. detergents) are present, significantly negatively-biased or false negative results can be obtained. If there is any evidence for the presence of surfactances in the soil, this method cannot be applied.Cross References:ISO 11074ISO 10381-5ISO 11464ISO 12404ISO 17381ISO/IEC Guide 98All current amendments available at time of purchase are included with the purchase of this document.
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发布单位或类别: 英国-英国标准学会
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