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Effects of Alum Coagulation on Speciation and Distribution of Disinfection Byproducts 明矾混凝对消毒副产物形态及分布的影响
发布日期: 2004-11-15
明矾凝固对消毒副产物(DBPs)分布的影响, 三卤甲烷(THMs)和卤乙酸(HAAs)在受控条件下进行评估 使用四种地表水的氯化条件。在发现的九个哈斯中 水、二卤乙酸(X2AAs)已被发现是所有区域的主要物种 原水和明矾处理过的水。明矾凝固往往会去除更多的水 单卤乙酸(XAAs)和三卤乙酸(X3AAs)的前体比 二卤乙酸(X2AAs)。明矾混凝处理水的HAA9/TTHM较低 与原水的比例比较。三卤甲烷溴掺入量的增加 明矾处理过的水的因子(BIFα)值与对照组相比具有统计学意义 原水。平均而言,在进行明矾凝固处理后,BIFα增加了54% 这四种不同的水域。这表明THM物种的变化有利于 更多的溴化化合物。然而,明矾混凝处理工艺的影响较小 对HAA溴掺入因子(BIFß)的影响大于对BIFα的影响。溴 在THM和HAA形成过程中,掺入因子(BIF)值随时间降低 过程,尤其是在反应时间的前10小时内。这表明 在初始阶段,溴化THM或HAAs的形成速度比氯化物种快 时期包括22个参考文献、表格和图表。
The impacts of alum coagulation on the distribution of disinfection byproducts (DBPs), trihalomethanes (THMs) and haloacetic acids (HAAs), were evaluated under controlled chlorination conditions using four surface waters. Among the nine HAAs found in waters, dihaloacetic acids (X2AAs) have been found to be the dominant species in all of the raw and alum treated waters. Alum coagulation tends to remove more monohaloacetic acids (XAAs) and trihaloacetic acids (X3AAs) precursors than that of dihaloacetic acids (X2AAs). Alum coagulation treated water had a lower HAA9/TTHM ratio compared with that of the raw water. The increase of THM bromine incorporation factors (BIFα) value of alum treated water was statistically significant in comparison with the raw water. On average, BIFα increased by 54% after the alum coagulation process in these four different waters. This indicated that THM speciations shifted in favor of the more brominated compounds. However, alum coagulation treatment process had less effect on HAA bromine incorporation factors (BIFß) than it did on BIFα. Bromine Incorporation Factor (BIF) values decreased with time in the THM and HAA formation processes, especially within the first 10 hours of the reaction time. This suggested that brominated THMs or HAAs formed faster than the chlorinated species in the initial period. Includes 22 references, tables, figures.
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发布单位或类别: 美国-美国给水工程协会
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