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Standard Test Method for Determination of Low Level Phthalates in Poly(Vinyl Chloride) Plastics by Solvent Extraction—Gas Chromatography/Mass Spectrometry 用溶剂萃取气相色谱/质谱法测定聚氯乙烯塑料中低含量邻苯二甲酸盐的标准试验方法
发布日期: 2023-03-15
1.1 本试验方法提供了一种通过对增塑聚氯乙烯制品进行溶剂萃取,然后通过气相色谱/质谱法分析提取物来定量六种邻苯二甲酸酯的程序。六种邻苯二甲酸酯,BBP、DBP、DEHP、DNOP、DINP和DIDP,用于说明如何实施该方法。 注1: 该方法可以扩展到各种聚合物基质中的其他邻苯二甲酸酯。 1.2 在该方法的上下文中,“低水平”被定义为1000 ppm。 1.3 以国际单位制表示的数值应视为标准。 1.4 本标准并非旨在解决与其使用相关的所有安全问题(如有)。本标准的使用者有责任在使用前制定适当的安全、健康和环境实践,并确定监管限制的适用性。 注2: 目前还没有与该标准等效的ISO。 1.5 本国际标准是根据世界贸易组织技术性贸易壁垒委员会发布的《关于制定国际标准、指南和建议的原则的决定》中确立的国际公认的标准化原则制定的。 ====意义和用途====== 5.1 邻苯二甲酸盐的鉴定和定量- DBP、BBP、DEHP、DNOP、DINP和DIDP是各种法规禁止或监测的邻苯二甲酸酯的代表。法规包括:欧盟指令2005/84/EC、美国《2008年消费品安全改进法案》第108节、日本厚生劳动省第336号指南(2010)和IEC 62321-8:2017。这些测试方法提供了一种识别和量化聚氯乙烯中邻苯二甲酸酯的程序。 5.2 其他成功用于分离和鉴定聚氯乙烯中邻苯二甲酸酯的技术包括TD-GC/MS(ASTM 第7823页 )、GC/MS、HPLC/UV、HPLC/MS、FTIR和GC/FID(火焰离子化检测器)。
1.1 This test method provides a procedure to quantify six phthalates by solvent extraction of plasticized PVC articles followed by analysis of the extract by gas chromatography/mass spectrometry. Six phthalates, BBP, DBP, DEHP, DNOP, DINP, and DIDP, are used to illustrate how to implement the method. Note 1: The method can be extended to other phthalates in a wide range of polymeric substrates. 1.2 Within the context of this method, “low level” is defined as 1000 ppm. 1.3 The values in SI units are to be regarded as standard. 1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Note 2: There is no known ISO equivalent to this standard. 1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee. ====== Significance And Use ====== 5.1 Identification and Quantification of Phthalates— DBP, BBP, DEHP, DNOP, DINP and DIDP are representative of the phthalates either banned or being monitored by a variety of regulations. Regulations include: EU—Directive 2005/84/EC, US—Consumer Product Safety Improvement Act of 2008 – section 108, Japan—Health, Labor and Welfare Ministry guideline No. 336 (2010) and IEC 62321-8:2017. These test methods provide a procedure to identify and quantify phthalates in PVC. 5.2 Other techniques successfully used to separate and identify phthalates in PVC include TD-GC/MS (ASTM D7823 ), GC/MS, HPLC/UV, HPLC/MS, FTIR, and GC/FID (flame ionization detector).
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归口单位: D20.70
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