Liming material — Determination of neutralizing value — Titrimetric methods
取样材料中和值的测定滴定法
发布日期:
2020-05-15
本文件规定了两种测定石灰材料中和值(NV)的方法。
方法A适用于除硅酸盐石灰材料以外的所有石灰材料。
注1硬石灰材料的例子有石灰石和白云石。软石灰材料的例子有白垩、泥灰和生石灰。
方法B适用于所有石灰材料。
两种方法都没有正确考虑含有超过3%P2O5的材料的潜在中和值。为了对含有超过3%P2O5的产品进行更准确的农艺评估,EN 14984[8]用于确定石灰效率。
注2 ISO 6598和ISO 7497中描述的方法可用于P2O5含量的测定。关于P分析的更多信息在参考文献[5]和[6]中给出。注3碳酸盐消耗H+并去除溶液中的酸度,随后解离为H2O和CO2。正磷酸盐的形式可以消耗H+,但不会解离成去除酸性的分子形式。用碱反滴定酸度,导致NV低估。
This document specifies two methods for the determination of the neutralizing value (NV) of liming materials.
Method A is applicable to all liming materials except silicate liming materials.
NOTE 1 Examples of hard liming materials are limestone and dolomite. Examples of soft liming materials are chalk, marl and burnt lime.
Method B is applicable to all liming materials.
Neither method correctly takes into account the potential neutralizing value of material containing more than 3 % P2O5. For a more accurate agronomic assessment of products containing more than 3 % P2O5, EN 14984[8] is used to determine the liming efficiency.
NOTE 2 The methods described in ISO 6598 and ISO 7497 can be used for the determination of P2O5 content. Further information on P analyses is given in References [5] and [6].
NOTE 3 Carbonate consumes H+ and removes acidity in solution with subsequent dissociation to H2O and CO2. Forms of orthophosphate can consume H+ but are not dissociated to molecular forms that remove acidity. The acidity is back titrated with alkali causing an underestimation of NV.