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Standard Test Methods for Chemical Analysis of Cast Iron—All Types 铸铁化学分析的标准试验方法&x2014;所有类型
发布日期: 2018-07-01
1.1 这些试验方法包括化学成分在以下范围内的生铁、灰铸铁(包括合金和奥氏体)、白口铸铁、可锻铸铁和球墨铸铁的化学分析: 要素 成分范围, % 铝 0.003至  0.50 锑 0.005至 0.03 砷 0.02  到 0.10 铋 0.001至  0.03 硼 0.001至 0.10 镉 0.001至 0.005 碳 1.25  到 4.50 铈 0.005至  0.05 铬 0.01  至30.00 钴 0.01  到 4.50 铜 0.03  到 7.50 领导 0.001至  0.15 镁 0.002至 0.10 锰 0.06  到 2.50 钼 0.01  到 5 镍 0.01  至36.00 磷 0.01  到 0.90 硒 0.001至 0.06 硅 0.10 至6.0 硫黄 0.005至  0.25 碲 0.001至 0.35 锡 0.001至 0.35 钛 0.001至 0.20 钨 0.001至 0.20 钒 0.005至 0.50 锌 0.005至 0.20 1.2 本标准中的试验方法包含在以下章节中: 小节 直接燃烧红外吸收法测定的石墨碳(1%-3%) 108–115 通过燃烧重量法测定碳总量(1.25%-4.50%)- 2012年停产 97–107 直流等离子体原子发射光谱法测定铈和镧(铈:0.003%-0.5%;镧:0.001%-0.30%) 237–245 原子吸收法测定的铬(0.006%-1.00%) 208–217 过硫酸氧化滴定法测定铬(0.05%-30.0%) 218–226 过硫酸氧化滴定法测定铬(0.05%-30.0%)- 1980年停产 144–151 离子交换电位滴定法测定钴(2.0%-4.5%) 53–60 亚硝基R盐分光光度法测定钴(0.01%-4.50%) 61–70 新铜试剂分光光度法测定铜(0.03%-7.5%) 116–125 硫化物沉淀-电沉积重量法测定铜(0.03%-7.5%) 81–88 离子交换原子吸收光谱法测定铅(0.001%-0.15%) 126–135 原子吸收光谱法测定镁(0.002%-0.10%) 71–80 高碘酸盐分光光度法测定锰(0.10%-2.00%) 9–18 用过硫酸亚砷酸盐滴定法测定锰(0.10%-3.5%) 152–159 离子交换-8-羟基喹啉重量法测定钼 257–264 硫氰酸盐分光光度法测定钼(0.01%-1.5%) 196–207 丁二酮肟重量法测定镍(0.1%-36.00%) 168–175 离子交换原子吸收光谱法测定镍(0.005%-1.00%) 176–185 碱度法测定磷(0.02%-0.90%) 160–167 钼蓝分光光度法测定磷(0.02%-0.90%) 19–30 重量法测定硅(0.1%-6.0%) 46–52 重量法测定硫- 1988年停产 30–36 硫通过燃烧碘酸盐滴定法(0。 005%至0.25 %)— 2012年停产 37–45 色谱重量法测定硫- 1980年停产 136–143 溶剂萃取原子吸收光谱法测定锡(0.002%-0.10 %) 186–195 通过硫化物沉淀碘量滴定法测定锡(0.01%-0.35 %) 89–96 二安替比林甲烷分光光度法测定钛(0.006%-0.35 %) 246–256 原子吸收光谱法测定钒(0.006%-0.15 %) 227–236 1.3 这些试验方法中未包括的碳和硫的测定程序可在试验方法中找到 E1019 . 1.4 中给出的一些组成范围 1.1 太宽,无法用单一方法涵盖,因此本标准包含一些元素的多种方法。用户必须通过将每个方法的范围和干扰部分中给出的信息与待分析合金的成分相匹配来选择适当的方法。 1.5 以国际单位制表示的数值应视为标准值。 1.6 本标准并非旨在解决与其使用相关的所有安全问题(如有)。本标准的用户有责任在使用前制定适当的安全、健康和环境实践,并确定监管限制的适用性。 具体危害说明见第节 6. 在这些方法的特别“警告”段落中。 1.7 本国际标准是根据世界贸易组织技术性贸易壁垒(TBT)委员会发布的《关于制定国际标准、指南和建议的原则的决定》中确立的国际公认标准化原则制定的。 ====意义和用途====== 4.1 这些金属和合金化学分析的试验方法主要用于测试此类材料是否符合成分规范,特别是ASTM委员会A04铸铁件管辖范围内的成分规范。 假设所有使用这些测试方法的人都是经过培训的分析员,能够熟练、安全地执行常见的实验室程序。预计工作将在适当的质量控制实践(如指南中所述)下,在配备适当的实验室中进行 E882 .
1.1 These test methods cover the chemical analysis of pig iron, gray cast iron (including alloy and austenitic), white cast iron, malleable cast iron, and ductile (nodular) iron having chemical compositions within the following limits: Element Composition Range, % Aluminum 0.003 to  0.50 Antimony 0.005 to  0.03 Arsenic 0.02  to  0.10 Bismuth 0.001 to  0.03 Boron 0.001 to  0.10 Cadmium 0.001 to 0.005 Carbon 1.25  to  4.50 Cerium 0.005 to  0.05 Chromium 0.01  to 30.00 Cobalt 0.01  to  4.50 Copper 0.03  to  7.50 Lead 0.001 to  0.15 Magnesium 0.002 to  0.10 Manganese 0.06  to  2.50 Molybdenum 0.01  to  5.00 Nickel 0.01  to 36.00 Phosphorus 0.01  to  0.90 Selenium 0.001 to  0.06 Silicon 0.10 to 6.0 Sulfur 0.005 to  0.25 Tellurium 0.001 to  0.35 Tin 0.001 to  0.35 Titanium 0.001 to  0.20 Tungsten 0.001 to  0.20 Vanadium 0.005 to  0.50 Zinc 0.005 to  0.20 1.2 The test methods in this standard are contained in the sections indicated below: Sections Carbon, Graphitic, by the Direct Combustion Infrared Absorption Method (1 % to 3 %) 108–115 Carbon, Total by the Combustion Gravimetric Method (1.25 % to 4.50 %)— Discontinued 2012 97–107 Cerium and Lanthanum by the Direct Current Plasma Atomic Emission Spectrometry Method (Ce: 0.003 % to 0.5 %; La: 0.001 % to 0.30 %) 237–245 Chromium by the Atomic Absorption Method (0.006 % to 1.00 %) 208–217 Chromium by the Peroxydisulfate Oxidation—Titration Method (0.05 % to 30.0 %) 218–226 Chromium by the Peroxydisulfate-Oxidation Titrimetric Method (0.05 % to 30.0 %)— Discontinued 1980 144–151 Cobalt by the Ion-Exchange—Potentiometric Titration Method (2.0 % to 4.5 %) 53–60 Cobalt by the Nitroso-R-Salt Spectrophotometric Method (0.01 % to 4.50 %) 61–70 Copper by the Neocuproine Spectrophotometric Method (0.03 % to 7.5 %) 116–125 Copper by the Sulfide Precipitation-Electrodeposition Gravimetric Method (0.03 % to 7.5 %) 81–88 Lead by the Ion-Exchange—Atomic Absorption Spectrometry Method (0.001 % to 0.15 %) 126–135 Magnesium by the Atomic Absorption Spectrometry Method (0.002 % to 0.10 %) 71–80 Manganese by the Periodate Spectrophotometric Method (0.10 % to 2.00 %) 9–18 Manganese by the Peroxydisulfate-Arsenite Titrimetric Method (0.10 % to 3.5 %) 152–159 Molybdenum by the Ion Exchange–8-Hydroxyquinoline Gravimetric Method 257–264 Molybdenum by the Thiocyanate Spectrophotometric Method (0.01 % to 1.5 %) 196–207 Nickel by the Dimethylglyoxime Gravimetric Method (0.1 % to 36.00 %) 168–175 Nickel by the Ion Exchange-Atomic Absorption Spectrometry Method (0.005 % to 1.00 %) 176–185 Phosphorus by the Alkalimetric Method (0.02 % to 0.90 %) 160–167 Phosphorus by the Molybdenum Blue Spectrophotometric Method (0.02 % to 0.90 %) 19–30 Silicon by the Gravimetric Method (0.1 % to 6.0 %) 46–52 Sulfur by the Gravimetric Method— Discontinued 1988 30–36 Sulfur by the Combustion-Iodate Titration Method (0.005 % to 0.25 %)— Discontinued 2012 37–45 Sulfur by the Chromatographic Gravimetric Method— Discontinued 1980 136–143 Tin by the Solvent Extraction-Atomic Absorption Spectrometry Method (0.002 % to 0.10 %) 186–195 Tin by the Sulfide Precipitation-Iodometric Titration Method (0.01 % to 0.35 %) 89–96 Titanium by the Diantipyrylmethane Spectrophotometric Method (0.006 % to 0.35 %) 246–256 Vanadium by the Atomic Absorption Spectrometry Method (0.006 % to 0.15 %) 227–236 1.3 Procedures for the determination of carbon and sulfur not included in these test methods can be found in Test Methods E1019 . 1.4 Some of the composition ranges given in 1.1 are too broad to be covered by a single method and therefore this standard contains multiple methods for some elements. The user must select the proper method by matching the information given in the Scope and Interference sections of each method with the composition of the alloy to be analyzed. 1.5 The values stated in SI units are to be regarded as standard. 1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 6 and in special “Warning” paragraphs throughout these Methods. 1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee. ====== Significance And Use ====== 4.1 These test methods for the chemical analysis of metals and alloys are primarily intended as referee methods to test such materials for compliance with compositional specifications, particularly those under the jurisdiction of ASTM Committee A04 on Iron Castings. It is assumed that all who use these test methods will be trained analysts capable of performing common laboratory procedures skillfully and safely. It is expected that work will be performed in a properly equipped laboratory under appropriate quality control practices such as those described in Guide E882 .
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