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现行 ASTM D7315-17(2023)
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Standard Test Method for Determination of Turbidity Above 1 Turbidity Unit (TU) in Static Mode 静态模式下1个浊度单位(TU)以上浊度测定的标准试验方法
发布日期: 2023-11-01
1.1 本试验方法包括水中浊度的静态测定。静态是指从其来源移除并在隔离仪器中进行测试的样品。(参见第节 4. .) 1.2 本试验方法适用于大于1.0浊度单位(TU)的浊度测量。测量范围的上端没有定义,因为该测试方法中描述的不同技术可以覆盖非常不同的范围。循环研究涵盖了0至4000浊度单位的范围,因为该范围内的仪器验证通常可以通过可一致复制的标准进行。 1.3 当通用校准标准适用于中列出的设计时,本试验方法中涵盖的许多浊度单位和仪器设计在校准中具有数值等效性 表1 .对定义值的通用校准标准的测量也将在这些技术中产生等效的结果。 1.3.1 在该试验方法中,校准标准通常以NTU值定义,但其他指定的浊度单位,如 表1 是等效的。例如,1 NTU形式津标准也是1 FNU、1 FAU、1 BU等。 1.4 本试验方法并不旨在涵盖高水平浊度测量的所有可用技术。 1.5 该测试方法在不同的天然水和废水上进行了测试,并采用了替代样品的标准。用户有责任确保该测试方法对未经测试的基质水的有效性。 1.6 根据高水平样品中的成分,拟议的样品制备和测量方法可能适用,也可能不适用。那些具有最高颗粒密度的样品通常被证明是最难测量的。在这些情况下,可以考虑替代测量方法,如过程监测方法。 1.7 本标准并不旨在解决与其使用相关的所有安全问题(如有)。本标准的使用者有责任在使用前制定适当的安全、健康和环境实践,并确定监管限制的适用性。 有关本程序中使用的所有化学品,请参阅MSDS。 1.8 本国际标准是根据世界贸易组织技术性贸易壁垒委员会发布的《关于制定国际标准、指南和建议的原则的决定》中确立的国际公认的标准化原则制定的。 ====意义和用途====== 5.1 经常监测本试验方法范围内规定水平的浊度,以帮助控制过程,监测水环境的健康和生物学,并确定环境事件(天气事件、洪水等)变化的影响。 )。在饮用水、工厂废水、食品和饮料加工用水以及许多其他依赖水的制造过程中,浊度通常是不可取的。去除通常通过混凝、沉淀和不同程度的过滤来完成。浊度的测量提供了污染的指标,是监测样品来源或过程中特性和/或质量的重要测量。 5.2 此测试方法确实与测试方法重叠 D6855 对于1到5 TU的范围。如果主要测量值低于1.0 TU,偶尔峰值高于该值,则试验方法 D6855 可能更适用。 对于持续高于1 TU的测量值,此测试方法适用。 5.3 该测试方法适用于浊度,例如在所有测量值超过1 NTU的水中发现的浊度。例子包括环境水(溪流、河流、湖泊、水库、河口)、与水污染控制厂(废水处理厂)相关的过程,以及涉及明显浊度水的各种工业过程。有关清洁水的测量,请参阅试验方法 D6855 。 5.4 应使用的特定技术或仪器类型的适当测量范围为80或以下 %相应仪器或技术的全尺寸能力。 高于此水平的测量可能不可靠。 5.4.1 不建议对水进行稀释,尤其是在具有快速沉降颗粒(即沉积物)的样品的情况下。建议选择覆盖预期范围的适当仪器设计,以避免进行稀释。 5.5 本标准中描述的技术可能无法测量样品的所有方面(吸收和散射)。水、悬浮物质或两者的某些特性可能会干扰样品的某些测量特性,例如特定仪器测量的光散射。 5.6 几种不同的技术可用于测量高- 液位浊度。根据应用和测量标准,某些技术可能更适合特定类型的样本。请参阅 表1 和 附录X1 其是帮助选择用于特定应用的最佳技术的流程图。 5.1.4 当测量高水平的浊度时,样品通常会包含显著的干扰,例如来自吸收颗粒、基质中的吸光度和快速沉降颗粒的干扰。这些可能会对一种测量技术如何应对浊度变化产生重大影响。通常情况下,谨慎的做法是进行一系列线性稀释,以确定测量的响应是否与稀释度相关。 在稀释比响应为线性的情况下,该技术可以充分考虑干扰。如果没有预期的响应,则应考虑另一种技术来确定是否可以获得更准确的测量结果。 5.7 在报告测量结果时,还应附上适当的单位。这些单位反映了用于生成测量值的技术。其目的是为用于生成测量结果的技术提供可追溯性,并在必要时提供与历史数据的更充分的比较。部分 7. 描述了每种类型的可追溯报告单元所基于的技术。 5.7.1 表1 包含可追溯到该技术的技术清单和相应的报告单位。 5.7.1.1 中的方法 表1 可以根据所使用的入射光源的类型划分为两组不同的设计。这些是宽带白色光源或提供400光谱输出的光源 nm至680nm范围内。这些光源包括多色光源,例如符合美国环保局方法180.1规定的方法所必需的光源,但如果各个波长落在规定范围内,也可以包括单色光源。第二组仪器使用在780范围内的近红外单色光源 nm至900nm。 这些设计在报告单位中是可区分的,并且总是以字母F开头。 5.7.1.2 对于不在这些报告范围内的特定设计,应以浊度单位(TU)报告浊度,并使用下标的波长值来表征所使用的光源。看见 7.4.3 。 5.7.1.3 中列出的那些设计 表1 包括ASTM小组委员会目前确定的那些。本文件未涵盖的未来设计可在方法小组委员会审查后纳入未来修订版。 5.7.1.4 请参阅第节 7. 了解有关仪器设计的更多细节。 5.7.1.5 部分 16 包含包含不同技术分类的精度和偏差数据。精度和偏差部分包括所有实验室的总体数据集和该数据集的较小部分,以提供该测试方法中所代表的技术所表现出的不同技术特征之间的比较。 5.8 该测试方法包括测量从水中采集的样本,并使用典型的实验室或便携式仪器进行分析。
1.1 This test method covers the static determination of turbidity in water. Static refers to a sample that is removed from its source and tested in an isolated instrument. (See Section 4 .) 1.2 This test method is applicable to the measurement of turbidities greater than 1.0 turbidity unit (TU). The upper end of the measurement range was left undefined because different technologies described in this test method can cover very different ranges. The round robin study covered the range of 0 to 4000 turbidity units because instrument verification in this range can typically be covered by standards that can be consistently reproduced. 1.3 Many of the turbidity units and instrument designs covered in this test method are numerically equivalent in calibration when a common calibration standard is applied across those designs listed in Table 1 . Measurement of a common calibration standard of a defined value will also produce equivalent results across these technologies. 1.3.1 In this test method calibration standards are often defined in NTU values, but the other assigned turbidity units, such as those in Table 1 are equivalent. For example, a 1 NTU formazin standard is also a 1 FNU, a 1 FAU, a 1 BU, and so forth. 1.4 This test method does not purport to cover all available technologies for high-level turbidity measurement. 1.5 This test method was tested on different natural waters and wastewater, and with standards that will serve as surrogates to samples. It is the user's responsibility to ensure the validity of this test method for waters of untested matrices. 1.6 Depending on the constituents within a high-level sample, the proposed sample preparation and measurement methods may or may not be applicable. Those samples with the highest particle densities typically prove to be the most difficult to measure. In these cases, and alternative measurement method such as the process monitoring method can be considered. 1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Refer to the MSDSs for all chemicals used in this procedure. 1.8 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee. ====== Significance And Use ====== 5.1 Turbidity at the levels defined in the scope of this test method are often monitored to help control processes, monitor the health and biology of water environments and determine the impact of changes in response to environmental events (weather events, floods, etc.). Turbidity is often undesirable in drinking water, plant effluent waters, water for food and beverage processing, and for a large number of other water-dependent manufacturing processes. Removal is often accomplished by coagulation, sedimentation, and various levels of filtration. Measurement of turbidity provides an indicator of contamination, and is a vital measurement for monitoring the characteristics and or quality within the sample’s source or process. 5.2 This test method does overlap Test Method D6855 for the range of 1 to 5 TU. If the predominant measurement falls below 1.0 TU with occasional spikes above this value, Test Method D6855 may be more applicable. For measurements that are consistently above 1 TU, this test method is applicable. 5.3 This test method is suitable to turbidity such as that found in all waters that measure above 1 NTU. Examples include environmental waters (streams, rivers, lakes, reservoirs, estuaries), processes associated with water pollution control plants (wastewater treatment plants), and various industrial processes involving water with noticeable turbidity. For measurement of cleaner waters, refer to Test Method D6855 . 5.4 The appropriate measurement range for a specific technology or instrument type that should be utilized is at or below 80 % of full-scale capability for the respective instrument or technology. Measurements above this level may not be dependable. 5.4.1 Dilutions of waters are not recommended, especially in the case of samples with rapidly settling particles (that is, sediments). It is recommended that an appropriate instrument design that covers the expected range be selected to avoid the need to perform dilutions. 5.5 Technologies described in this standard may not measure all aspects (absorption and scatter) of a sample. Some of the properties of the water, the suspended material, or both may interfere with the certain measured property of the sample, such as the scattering of light that the particular instrument is measuring. 5.6 Several different technologies are available for use in the measurement of high-level turbidity. Some technologies may be better suited for specific types of samples, depending on the application and measurement criteria. Please refer to Table 1 and Appendix X1 which is a flow chart to help assist in selecting the best technology for the specific application. 5.6.1 When measuring high levels of turbidity the samples will often contain significant interferences such as that from absorbing particles, absorbance in the matrix, and rapidly settling particles. These may have a significant impact on how one measurement technology responds to changes in turbidity. Often times it will be prudent to run a series of linear dilutions to determine if the measured response was expected relative to the dilution. In cases where the response to dilution ratio is linear, the technology may be adequately accounting for the interferences. If the response is not expected, another technology should be considered to determine if a more accurate measurement could be obtained. 5.7 When reporting the measured result, appropriate units should also be attached. The units are reflective of the technology used to generate the measurements. The intention is to provide traceability for the technology used to generate the measured result, and if necessary, provide more adequate comparison to historical data. Section 7 describes technology that each type of traceable reporting units is based. 5.7.1 Table 1 contains the list of technologies and respective reporting units that will be traceable to that technology. 5.7.1.1 The methods in Table 1 can be broken down into two distinct groups of designs which are based on the type of incident light source used. These are broad-band white light source or light sources that provide a spectral output in the 400 nm to 680 nm range. These include polychromatic light sources, such as those that are necessary to comply with regulatory method U.S. EPA Method 180.1, but also can include mono-chromatic light sources if the respective wavelength falls within the specified range. The second group of instruments uses a near IR monochromatic light source that is in the range of 780 nm to 900 nm. These designs are distinguishable in the reporting units and will always begin with the letter F. 5.7.1.2 For a specific design that falls outside of these reporting ranges, the turbidity should be reported in turbidity units (TU) with a subscripted wavelength value to characterize the light source that was used. See 7.4.3 . 5.7.1.3 Those designs listed in Table 1 cover those that were currently identified by the ASTM subcommittee. Future designs that are not covered in this document may be incorporated into a future revision after review by the method subcommittee. 5.7.1.4 See Section 7 for more details regarding instrument designs. 5.7.1.5 Section 16 contains precision and bias data that incorporates the different classifications of technologies. The precision and bias section includes the overall data set of all laboratories and smaller segments of this data set to provide comparisons across distinguishing technological features that are exhibited by those technologies that are represented in this test method. 5.8 This test method covers the measurement of samples collected from waters and analyzed using typical laboratory based or portable-based instruments.
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