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Degradation of Disinfection Byproducts in the Presence of Fe(0) and Iron Corrosion Products 存在Fe(0)和铁腐蚀产物时消毒副产物的降解
发布日期: 2005-06-17
铸铁和球墨铸铁管在美国和美国各地的配水系统中使用 在欧洲。铁金属(Fe(0))和铁腐蚀过程中产生的Fe(II)是有效的 还原剂已被证明能促进多种卤代化合物的还原 有机化学品。因此,进行了批量实验,以研究a的降解 在含有铁(0)和含铁矿物的情况下产生多种消毒副产物(DBPs) 铁(II)和铁(II)吸附在氧化铁表面。大多数DBP测试结果完全符合要求 在Fe(0)存在下脱卤,生成无毒终产物。正如所料,退化 存在Fe(II)矿物(例如磁铁矿)和吸附Fe(II)的速率比 含Fe(0)。与之竞争的氧化剂(如溶解氧)的作用是混合的,因为 研究了快速降解(即传质受限降解)化合物的降解速率 未受影响,但观察到反应较慢的滞后阶段(i。 e、 表面反应有限公司) 化合物。这项研究的结果表明,非生物降解可能在 DBP在配电系统中的命运,也提出了DBP的可能治疗策略 停止供水。包括7个参考文献、表格、图表。
Cast iron and ductile iron pipes are in use in water distribution systems throughout the U.S. and in Europe. Iron metal (Fe(0)) and the Fe(II) produced during corrosion of iron are potent reductants that have been shown to promote the reduction of a wide variety of halogenated organic chemicals. Thus, batch experiments were performed to investigate the degradation of a wide variety of disinfection byproducts (DBPs) in the presence of Fe(0), iron minerals containing Fe(II), and Fe(II) sorbed onto iron oxide surfaces. Most DBPs tested were completely dehalogenated in the presence of Fe(0) to non-toxic endproducts. As expected, degradation rates in the presence of Fe(II) minerals (e.g., magnetite) and sorbed Fe(II) were slower than with Fe(0). The effects of a competing oxidant such as dissolved oxygen were mixed, as the degradation rates of rapidly degraded (i.e. mass transfer limited degradation) compounds were unaffected while a lag phase was observed for slower reacting (i.e. surface reaction limited) compounds. The results of this research suggest that abiotic degradation may play a role in the fate of DBPs in distribution systems and also suggests a possible treatment strategy for DBP removal from water supplies. Includes 7 references, table, figures.
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发布单位或类别: 美国-美国给水工程协会
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