Water quality. Determination of selected polybrominated diphenly ether (PBDE) in whole water samples. Method using solid phase extraction (SPE) with SPE-disks combined with gas chromatography-mass spectrometry (GC-MS)
水质 全水样中所选多溴联苯醚(PBDE)的测定 固相萃取(SPE)结合气相色谱-质谱(GC-MS)的方法
发布日期:
2015-09-30
BS EN 16694:2015规定了测定六种选定多溴化物的方法
表1中列出的二苯醚(PBDE),代表工业溴化二苯醚
(BDE)以质量浓度存在于水样中≥ 每种同系物0025纳克/升。方法
使用固相萃取盘与气相色谱-质谱联用
光谱分析(GC-MS)。适用于含悬浮物地表水中多溴二苯醚的分析
颗粒物(SPM)高达500 mg/l(整个水样)、饮用水和地下水。这个
定量限(LOQ)根据ISO/TS 13530,在重复性基础上确定
在再现性条件下测定程序空白。该方法可用于分析表1中未列出的其他溴二苯醚同系物或其他类型的溴二苯醚
水然而,重要的是在使用前验证其适用性。交叉引用:EN ISO 3696ISO 3696EN ISO 5667-1ISO 5667-1EN ISO 5667-3ISO 5667-3ISO 8466-1EN 16377 EN ISO 22032ISO 22032EN ISO 22892ISO 22892ISO 5725-2ISO/TS 135302000/60/EC2008/105/EC2009/90/EC2013/39/EUSANCO/12571/2013购买本文件时提供的所有当前修订版。
BS EN 16694:2015 specifies a method for the determination of six selected polybrominated
diphenyl ethers (PBDE) listed in Table 1, representative for technical brominated diphenyl ethers
(BDE) in water samples in mass concentrations ≥ 0,025 ng/l for each individual congener. The method
uses solid-phase extraction with SPE-disks in combination with gas chromatography-mass
spectrometry (GC-MS). It is applicable to the analysis of PBDE in surface water containing suspended
particulate matter (SPM) up to 500 mg/l (whole water samples), drinking water and groundwater. The
limit of quantification (LOQ) was determined according to ISO/TS 13530, on the basis of replicate
determinations of the procedural blank, carried out under reproducibility conditions.This method may be used for the analysis of other BDE congeners not listed in Table 1 or other types of
water. However, it is important to verify its applicability before use.Cross References:EN ISO 3696ISO 3696EN ISO 5667-1ISO 5667-1EN ISO 5667-3ISO 5667-3ISO 8466-1EN 16377EN ISO 22032ISO 22032EN ISO 22892ISO 22892ISO 5725-2ISO/TS 135302000/60/EC2008/105/EC2009/90/EC2013/39/EUSANCO/12571/2013All current amendments available at time of purchase are included with the purchase of this document.