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Approaches for the Identification of New Ozonation Byproducts in Drinking Water 饮用水中新的臭氧氧化副产物的鉴定方法
发布日期: 2003-11-02
已知大量未经确认的副产品来自 臭氧与天然有机物(NOM)在预氧化处理中的反应 饮用水。阐明这些臭氧氧化副产物的性质和特性 受到两个复杂因素的阻碍。首先是固有的水性 其中许多化合物的溶解性,这使得它们能够从 水是很难实现的。第二是缺乏特定潜力的既定身份 副产品,使目标分析方法复杂化。为了克服这些 在挑战中,我们通过各种方法完成了副产品识别的任务 涉及水性官能团特定衍生反应。 描述了羰基化合物的水性官能团特异性衍生化 (多功能醛和酮)和环氧化合物。这些程序增强了 分析物的可萃取性,并为特定化合物提供分析“标志” 上课。衍生化合物通过固相萃取(SPE)进行萃取,并且 部分病例经进一步衍生化后,用气相色谱-质谱法进行分析 光谱分析(GC-MS)。 包括18个参考文献、图表。
Significant quantities of largely unidentified byproducts are known to be produced from the reactions of ozone and natural organic matter (NOM) during preoxidation treatment of drinking water. The elucidation of the nature and identity of these ozonation byproducts is hindered by two complicating factors. The first is the inherent aqueous solubility of many of these compounds, which renders their efficient extraction from water difficult to achieve. Second is the lack of established identity of specific potential byproducts, which complicates targeted analytical approaches. To overcome these challenges, we have approached the task of byproduct identification by methods involving aqueous functional group-specific derivatization reactions. Aqueous functional group-specific derivatizations are described for carbonyls (multifunctional aldehydes and ketones) and epoxides. These procedures enhance the extractability of the analytes and provide an analytical "flag" for the specific compound classes. Derivatized compounds are extracted by solid phase extraction (SPE) and, in some cases after further derivatization, analyzed by gas chromatography-mass spectrometry (GC-MS). Includes 18 references, figures.
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发布单位或类别: 美国-美国给水工程协会
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