Unintentional, indirect wastewater reuse is occurring as upstream wastewater treatment
plant (WWTP) discharges impact downstream drinking water treatment plants. As part of a
project to evaluate the contribution of wastewater to disinfection byproduct (DBP) formation in
drinking water, one of the objectives was to compare different WWTP processes for the control
of dissolved organic carbon and nitrogen (DOC and DON), and DBP precursors in effluent
organic matter (EfOM).
Nitrification plays a key role in determining the quality of EfOM in terms of traditional
wastewater parameters, natural organic matter character, and DBP-related parameters. Some
nitrification strongly altered the levels of total Kjeldahl nitrogen (TKN), ammonia (NH3-N),
DON, carbonaceous biochemical oxygen demand (CBOD), DOC, ultraviolet absorbance (UVA),
and chemical oxygen demand. Good nitrification (NH3-N <2 mg/L) augmented the changes for
TKN, NH3-N, and CBOD; reduced the concentration of biodegradable organic carbon (BDOC);
and dramatically changed the ratio of BDOC/DOC. During wastewater treatment, some of the
particulate and DON was transformed to biomass, NH3-N, nitrite, nitrate, and/or nitrogen gas,
whereas a portion of the DOC was transformed to biomass, carbon dioxide, methane, and/or
other gases. Although nitrification reduced the level of UVA, it resulted in an increase in
specific UVA (SUVA). This was probably due to preferential removal of the less UV-absorbing
(non- humic) portion of the DOC during biological treatment.
A reduction in DOC and UVA corresponded to less precursors for haloacetic acids,
whereas removal of DON resulted in less precursors for nitrogenous DBPs (e.g.,
haloacetonitriles, N-nitrosodimethylamine). However, on a central tendency basis,
trihalomethane precursors were relatively recalcitrant. This information is being used to better
understand the impact of improvements in WWTP water quality on DBP precursor loadings in
EfOM-impacted drinking-water supplies. Includes 18 references, tables, figures.