BS EN 62321-8:2017规定了两种标准技术和两种信息技术 邻苯二甲酸二异丁酯（DIBP）、邻苯二甲酸二正丁酯（DBP）、苄基丁基的测定 邻苯二甲酸酯（BBP）、邻苯二甲酸二（2-乙基己基）酯（DEHP）、邻苯二甲酸二正辛酯（DNOP）、二异壬基 电工产品聚合物中的邻苯二甲酸酯（DINP）和邻苯二甲酸二异癸酯（DIDP）。 气相色谱-质谱（GC-MS）和气相色谱-质谱 光谱分析（Py/TD-GC-MS）技术在本文件的规范性部分进行了描述。气相色谱-质谱法被认为是定量测定 DIBP、DBP、BBP、DEHP、DNOP、DINP和DIDP在50 mg/kg至2000 mg/kg范围内。 GC-MS与热解器/热脱附（TD）附件相结合，适用于 DIBP、DBP、BBP、DEHP、DNOP、DINP和DIDP的筛选和半定量分析 在100 mg/kg范围内用作电工产品部件的聚合物中 至2000毫克/千克。IAMS技术适用于DIBP、DBP、， BBP、DEHP、DNOP、DINP和DIDP。气相色谱法测定DBP和DIBP、DEHP和DNOP 由于峰值和质谱分辨率的限制，尚未建立IAMS。LC-MS技术仅限于测定BBP、DEHP、DNOP、DINP和 迪普。由于存在峰值和峰值，尚未建立LC-MS测定DBP和DIBP的方法 质谱分辨率限制。流程图描述了规范性Py/TD-GC-MS和GC-MS方法如何提供信息 方法采用离子连接质谱（IAMS）与直接进样探针联用 （DIP）和液相色谱-质谱（LC-MS）可用于 本文件的附件。这四种试验方法已通过PE（聚乙烯）和PVC的试验进行了评估 （聚氯乙烯）含有约450 mg/kg至450 mg/kg邻苯二甲酸盐的材料 30000 mg/kg，如本文件规范性和信息性部分所述。使用 本文件中描述的其他聚合物类型、邻苯二甲酸盐化合物或 上述规定以外的浓度范围尚未具体评估。交叉引用:IEC 62321-1:2013 IEC 62321-6:2015ISO 3696:1987ISO/IEC指南98-3:2008 Ed 1IEC 62321-2:2013ISO/IEC 17025:2005 Ed 1EN 14372:2004购买本文件时提供的所有当前修订均包含在购买本文件中。

BS EN 62321-8:2017 specifies two normative and two informative techniques for the determination of di-isobutyl phthalate (DIBP), di-n-butyl phthalate (DBP), benzylbutyl phthalate (BBP), di-(2-ethylhexyl) phthalate (DEHP), di-n-octyl phthalate (DNOP), di-isononyl phthalate (DINP) and di-iso-decyl phthalate (DIDP) in polymers of electrotechnical products. Gas chromatography-mass spectrometry (GC-MS) and gas chromatography-mass spectrometry (Py/TD-GC-MS) techniques are described in the normative part of this document.The GC-MS method is considered the referee technique for the quantitative determination of DIBP, DBP, BBP, DEHP, DNOP, DINP and DIDP in the range of 50 mg/kg to 2 000 mg/kg.The GC-MS coupled with a pyrolyzer/thermal desorption (TD) accessory is suitable for screening and semi-quantitative analysis of DIBP, DBP, BBP, DEHP, DNOP, DINP, and DIDP in polymers that are used as parts of the electrotechnical products in the range of 100 mg/kg to 2 000 mg/kg.The IAMS technique is suitable for screening and semi-quantitative analysis of DIBP, DBP, BBP, DEHP, DNOP, DINP, and DIDP. Determination of DBP and DIBP, DEHP and DNOP by IAMS has not been established due to peak and mass spectral resolution limitations.The LC-MS technique is limited to the determination of of BBP, DEHP, DNOP, DINP, and DIDP. Determination of DBP and DIBP by LC-MS has not been established due to peak and mass spectral resolution limitations.A flow chart depicting how the normative Py/TD-GC-MS and GC-MS methods and informative methods using ion attachment mass spectrometry (IAMS) coupled with direct injection probe (DIP) and liquid chromatography-mass spectrometry (LC-MS) can be used are provided in annexes of this document.These four test methods have been evaluated by the test of PE (polyethylene) and PVC (polyvinyl chloride) materials containing individual phthalates between ~450 mg/kg to 30 000 mg/kg as depicted in the normative and informative parts of this document. The use of the four methods described in this document for other polymer types, phthalate compounds or concentration ranges other than those specified above has not been specifically evaluated.Cross References:IEC 62321-1:2013 IEC 62321-6:2015ISO 3696:1987ISO/IEC GUIDE 98-3:2008 Ed 1IEC 62321-2:2013ISO/IEC 17025:2005 Ed 1EN 14372:2004All current amendments available at time of purchase are included with the purchase of this document.