1.1
This practice covers the use of Fresnel-reflecting concentrators that use the sun as a source of ultraviolet (UV) and longer wavelength radiation. Such devices are used in the outdoor accelerated exposure testing of plastics.
1.2
This practice provides a procedure for performing outdoor accelerated exposure testing of plastics using a Fresnel-reflector outdoor accelerated weathering test machine. The apparatus is described herein and in Practice
G90
more completely.
1.3
This practice is applicable to a range of plastic materials including, but not limited to, plastic films, sheets, laminates, and extruded and molded products in a variety of shapes and sizes, as specified in
8.2 and
8.3
.
1.4
This practice describes test conditions that attempt to simulate plastics exposures in desert and subtropical climates. Specimen preparation, property testing procedures, and the evaluation of results are covered in existing test methods or specifications for specific materials.
1.5
The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.6
This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
Specific precautionary statements are given in Section
7
.
Note 1:
This standard is equivalent to ISO 877-3: 2009.
1.7
This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
====== Significance And Use ======
4.1
This practice involves the concentration of sunlight by a system of plane mirrors, arranged to simulate a parabolic trough focused on an air-cooled target board on which the test specimens are mounted. Exposure cycles with and without water spray that are commonly used for this method are described in
Table 1
. Other exposure cycles not listed in
Table 1
can be used, upon consensual agreement between interested parties.
(A)
This is the cycle specified in Procedure C of Practice
D4141/D4141M
.
4.1.1
Accelerated outdoor exposure tests performed using this practice in an absence of a programmed moisture cycle are intended to simulate conventional exposure testing on racks facing the equator in desert and arid regions.
4.1.2
Accelerated outdoor exposure tests performed using this practice with a programmed moisture cycle shall possess the feature of spraying high purity water on the specimens in a regular, periodic fashion that is intended to simulate the results of conventional exposure testing on fixed racks facing the equator in subtropical, semi-humid, and temperate regions. Water-spray cycles that are recommended by this practice are given in
Table 1
.
4.2
The effectiveness of the Fresnel-reflector accelerated outdoor weathering test machines depends primarily on the amount and character of the UV in the direct-beam component of sunlight.
Note 2:
Use of the apparatus in regions of moderate- to high-diffuse irradiance will reduce the test machine's effectiveness substantially for providing concentrated UV in the target (specimen) area.
4.3
Testing to specific levels (quantities) of solar ultraviolet radiant exposure is recommended. Elapsed time exposure-level determinations shall not be used for testing with this practice. Testing to specific levels of UV irradiation, whether to total UV or within selected wavebands, is an effective method for improving agreement between wintertime and summertime testing on the Fresnel-reflector weathering-test machines. Other seasonal factors such as temperature and time of wetness can affect the weathering of test specimens significantly.
4.4
The weathering machines described provide for specimen cooling that reduces thermal problems in most materials. It is recommended that monthly temperature measurements be performed on heat-sensitive plastics to record the typical monthly test specimen temperatures.
Note 3:
It is possible for heat-sensitive plastic materials and thick specimens that are self-insulating to exhibit thermal-induced degradation that is unrealistic compared to natural weathering. Clear, thin-film photodegradable plastics are not recommended for testing with this practice for this reason.
4.5
Since the natural environment varies with respect to time, geography, and topography, it can be expected that the effects of natural exposure will vary accordingly. Furthermore, all materials are not affected equally by increased irradiance and temperature. The quantitative correlation between exposures conducted in accordance with this practice and those conducted under specified natural exposure conditions will therefore vary with the type and composition of the material.
4.6
While reference materials tested in accordance with this practice and Practices
G7/G7M
and
D1435
are useful for providing information on the relationship between accelerated and real-time tests, the acceleration factor found for the reference material cannot be used to extrapolate results of the accelerated test to predict lifetimes under natural exposure except for the specific material for which the relationship has been established.