Bench-Scale Testing Results: Removal of Endocrine-Disrupting Compounds, Pharmaceuticals and Personal Care Products by Conventional and Advanced Drinking Water Treatment Processes
实验室规模测试结果:通过传统和先进的饮用水处理工艺去除内分泌干扰物、药物和个人护理产品
Endocrine-disrupting compounds, pharmaceuticals and personal care products (EDC/PPCPs)
have been linked to a variety of adverse effects on wildlife. Some public and regulatory agencies
view EDC/PPCP compounds in drinking water as a potential human health risk. Pesticides and
herbicides can be EDCs and have been detected in surface and finished drinking waters since the
1970s. However, over the past decade as analytical techniques to detect parts-per-trillion levels of
organic compounds, many industrial-produced chemicals have been detected in finished
wastewater, industrial runoff, rivers, drinking water sources, and even finished drinking water.
This paper is based upon results from bench-scale testing on an AwwaRF project
#2758. Researchers, consultants, and utilities will be interested in this paper as it
addresses actual removal of emerging contaminants (in this study 67 target compounds) spanning
a wide range of chemical structures, and will aid in design of future bench and pilot-scale tests
for evaluating EDC/PPCPs. Bench-scale experiments have been conducted in model waters with natural organic matter and
four natural waters from around the United States. The waters were spiked with a suite of EDC/PPCP
compounds (initial concentration of 50 to 500 ng/L). Each water spiked with the EDC/PPCP
compound mixture was subjected to several parallel bench-scale treatments that include: alum and ferric
coagulation at multiple pH levels; chemical softening (pH 9, >11); chlorination (SDS
conditions); ozonation (Giardia inactivation levels, plus hydrogen peroxide addition);
activated carbon adsorption (2 PACs with four hour contact times at various dosages); deadend
membrane filtration (negatively charged/hydrophobic UF and NF membrane); and, biological
batch and column tests. Additional UV-photolysis tests and limited biodegradation experiments
are planned. LC-MS/MS & GC-MS/MS methods were used to analyze the suite of compounds.
Supplemental experiments using tritium (3H) labeled estradiol were conducted with PAC
and membrane tests. Pilot- and full-scale testing will be conducted during subsequent phases of
the project. Includes 2 references, table, figures.