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Standard Test Method for Determination of Peroxides in Butadiene 丁二烯中过氧化物测定的标准试验方法
发布日期: 2023-03-01
1.1 本试验方法包括丁二烯中过氧化物的测定。 1.2 该试验方法涵盖1 mg/kg至10 毫克/千克的有效氧。 1.3 以国际单位制表示的数值应视为标准。本标准中不包括其他计量单位。 1.4 本标准并非旨在解决与其使用相关的所有安全问题(如有)。本标准的使用者有责任在使用前制定适当的安全、健康和环境实践,并确定监管限制的适用性。 1.4.1 建议用户就本试验方法程序和相关活动的安全操作进行液化石油气安全培训。 1.5 本国际标准是根据世界贸易组织技术性贸易壁垒委员会发布的《关于制定国际标准、指南和建议的原则的决定》中确立的国际公认的标准化原则制定的。 ====意义和用途====== 4.1 由于丁二烯中过氧化物的固有危险,通常会对其存在设定规格限制。该试验方法将提供可用于测定商用丁二烯样品中过氧化物含量的值。 4.2 丁二烯多过氧化物是丁二烯和氧气之间可能发生的反应的一种非常危险的产物。据报道,过氧化物是储存丁二烯的容器发生剧烈爆炸的原因。
1.1 This test method covers the determination of peroxides in butadiene. 1.2 This test method covers the concentrations range of 1 mg/kg to 10 mg/kg as available oxygen. 1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.4.1 The user is advised to obtain LPG safety training for the safe operation of this test method procedure and related activities. 1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee. ====== Significance And Use ====== 4.1 Due to the inherent danger of peroxides in butadiene, specification limits are usually set for their presence. This test method will provide values that can be used to determine the peroxide content of a sample of commercial butadiene. 4.2 Butadiene polyperoxide is a very dangerous product of the reaction between butadiene and oxygen that can occur. The peroxide has been reported to be the cause of some violent explosions in vessels that are used to store butadiene.
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归口单位: D02.D0.04
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