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现行 ISO 4504:2023
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Plastics — Polyethylene (PE) — Determination of co-monomer content by solution state 13C-NMR spectrometry 塑料.聚乙烯(PE).溶液状态13C-NMR光谱法测定共聚单体含量
发布日期: 2023-06-16
本文件规定了两种通过溶液态13C-NMR光谱法(核磁共振光谱法)测定聚乙烯产品共聚单体含量的方法: —?方法A:逆门控去耦法。 —?方法B:偏振转移法增强的不敏感核; 该文献适用于其它1-烯烃单体的含量小于50%质量分数的乙烯共聚物。 该文献不适用于乙烯均聚物或其中乙烯与两种或更多种1-烯烃共聚单体聚合的共聚物。

This document specifies two methods for the determination of co-monomer contents of polyethylene products by solution state 13C-NMR spectrometry (nuclear magnetic resonance spectrometry):

method A: inverse gated decoupling method.

method B: insensitive nuclei enhanced by polarization transfer method;

This document is applicable to copolymers of ethylene having a content of other 1-olefinic monomers of less than a mass fraction of 50 %.

This document is not applicable to ethylene homopolymers or copolymers in which ethylene is polymerized with two or more type 1-olefin comonomers.

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归口单位: ISO/TC 61/SC 9
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