1.1 本标准提供了开发和描述使用波长色散X射线光谱仪进行固体金属、矿石和相关材料元素分析的分析程序的指南。本文讨论的材料形式包括固体、粉末和通过化学和物理过程制备的固体形式，例如硼酸盐熔融和压块。 1.2 本指南中不讨论液体，因为在金属和采矿实验室中很少遇到液体。 然而，含水液体可以通过硼酸盐熔合来制造固体样本，并且可以配备X射线光谱仪来直接处理液体。 1.3 本指南的某些规定可能适用于能量色散X射线光谱仪的使用。 1.4 单位- 以国际单位制表示的数值应视为标准值。本标准不包括其他计量单位。 1.5 本标准并非旨在解决与其使用相关的所有安全问题（如有）。 本标准的用户有责任在使用前制定适当的安全、健康和环境实践，并确定监管限制的适用性。 1.6 本国际标准是根据世界贸易组织技术性贸易壁垒（TBT）委员会发布的《关于制定国际标准、指南和建议的原则的决定》中确立的国际公认标准化原则制定的。 ====意义和用途====== 5.1 X射线荧光光谱法可以准确测定各种固体和液体材料中的金属和许多非金属元素。本指南涵盖了X射线光谱分析方法中应包含的信息，并为用户确定达到可接受精度所需的最佳条件提供了指导。 5.2 测定的准确性是校准算法、样品制备和样品均匀性的函数。 要取得可接受的结果，必须密切关注这些领域的各个方面。 5.3 本指南中讨论的所有概念都在许多已出版的文本和科学文献中进行了详细探讨。

1.1 This standard provides guidelines for developing and describing analytical procedures using a wavelength dispersive X-ray spectrometer for elemental analysis of solid metals, ores, and related materials. Material forms discussed herein include solids, powders, and solid forms prepared by chemical and physical processes such as borate fusion and pressing of briquettes. 1.2 Liquids are not discussed in this guide because they are much less frequently encountered in metals and mining laboratories. However, aqueous liquids can be processed by borate fusion to create solid specimens, and X-ray spectrometers can be equipped to handle liquids directly. 1.3 Some provisions of this guide may be applicable to the use of an energy dispersive X-ray spectrometer. 1.4 Units— The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee. ====== Significance And Use ====== 5.1 X-ray fluorescence spectrometry can provide an accurate determination of metallic and many non-metallic elements in a wide variety of solid and liquid materials. This guide covers the information that should be included in an X-ray spectrometric analytical method and provides direction to the user for determining the optimum conditions needed to achieve acceptable accuracy. 5.2 The accuracy of a determination is a function of the calibration algorithm, the sample preparation, and the sample homogeneity. Close attention to all aspects of these areas is necessary to achieve acceptable results. 5.3 All concepts discussed in this guide are explored in detail in a number of published texts and in the scientific literature.